A comparative study on metal–metal interaction in binuclear two- and three-coordinated d10-metal complexes

Cuprophilic Interactions in and between Molecular Entities

“…Che (48)]. [17,77] TheC u-Cu distances of 44 (2.731(2) )a nd 45 (2.790(5) )w ere shorter than those of the acetonitrile-bound complexes 47 (2.8096(9) )a nd 48 (2.810(2) ), and 46 (2.905 ). These structuralp arameters indicated ap ositivec orrelation between the Cu-Cu separations and the Cu-L/X interaction strengths.…”

“…[8][9][10][11][12][13][14][15][16] The existence of Au I -Au I interactions was corroborated by UV/Vis and resonance Raman spectroscopic investigations of the lowest-energy dipole-alloweda bsorptionb and of dinuclear gold species. [17,18] The strengths of aurophilicity weree stimated to be approximately 7-11kcal mol À1 ,c omparable to that of hydrogen bonding. [19][20][21] To date, the most accepted theory on the origin of the existence of aurophilicity is based on relativistic effects.…”

“…[4,5,38] Spectroscopic investigationso nt he presence of Cu I -Cu I interactions, particularly intermolecular cuprophilicity,a re more reliable but, unfortu-nately,l ess documented. [17,77] As such, different conclusions have been drawn for their existence, [78,79] and,t herefore, the presence of cuprophilic interactions is still under debates.…”

Synthesis, Structures, and Luminescent Properties of Two Four‐connected Polymers Based on 2, 2‐Dimethylsuccinic Acid

“…[30] As shown in Figure 7, the excitation spectrum was excited at 366 nm, the strong blue-photoluminescence emission spectrum is located at 487 nm for 1. The excitation spectrum was excited at 352 nm and the strong blue photoluminescence emission spectrum is located at 467 nm for 2.…”

A 3-D silver(I) polymer with 5,6-dihydro-1,4-dithiin-2,3-dicarboxylate ligand, showing an unusual 6-connected (412.63)2(49.66) topology

“…So far, silver(I) coordination complexes have attracted considerable interest in inorganic and supramolecular chemistry due to the coordinative flexibility of Ag I (linear, trigonal, tetrahedral, or octahedral coordination modes). On the other hand, Ag I centers can form Ag⋯Ag argentophilic interactions [5][6][7], which may give rise to discovery of novel structural motifs. Among various ligands, the versatile aromatic benzene-, naphthalene-, anthracene-, and pyrene-based di-and multi-carboxylate ligands have been successfully employed and well documented in the preparation of various carboxylato-containing metal-organic coordination complexes with useful properties [6a,8].…”