A comparative study of the corrosion performance of titanium (Ti), titanium nitride (TiN), titanium dioxide (TiO2) and nitrogen-doped titanium oxides (N–TiO2), as coatings for biomedical applications

Wang, Hefeng; Zhang, Rui; Yuan, Zhi; Shu, Xuefeng; Liu, Erqiang; Zhi-jun, Han

doi:10.1016/j.ceramint.2015.05.153

Cited by 67 publications

(21 citation statements)

References 44 publications

(42 reference statements)

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“…It was observed, that this increases the life span of surgical implants and prostheses. Coatings, among others with PVD method, enable to obtain a gradient diffusion layer of sufficient thickness and adhesion, which ensures long-lasting abrasion-resistant surface [4].…”

Section: Introductionmentioning

confidence: 99%

Evaluation of scratch resistance of nitride coatings on Ti grade 2

2017

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Abstract. Hard coatings limiting direct contact of material susceptible to wear are applied in order to improve resistance to abrasive wear. The key importance in using anti-wear coatings has their adhesion to substrate and differences in mechanical properties of the coating and substrate, particularly their Young's module. Studies have analyzed merits of applying nitride coatings TiAlN, AlTiN and hybrid coating TiAlN/TiSiN on titanium substrate ASTM grade 2. For that purpose, nanohardness and scratch tests for each coating were conducted. Apparatus of Anton Paar Company was used in these studies -ultra-high resolution nanoindenter and micro combi tester. Due to the fact, that surface roughness is a significant parameter affecting properties of the surface layer, the first appointed parameters were Sa roughness with a use of optical profilometer Bruker Contour GT. Obtained results suggest the best adhesive grip of hybrid coating TiAlN/TiSiN compared with other tested. The weakest adhesion to titanium grade 2 has TiAlN coating, on which in scratch test has been observed significantly faster total damage, in comparison with other tested. Research results will provide the input data for numerical analysis, enabling fast receiving effects of applying tested coatings without the need to carry out time-consuming research.

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Section: Introductionmentioning

confidence: 99%

Evaluation of scratch resistance of nitride coatings on Ti grade 2

2017

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“…Regarding the EIS results based on Nyquist diagram, TiO 2 system exhibited a higher capacitive capacity and a bigger impedance value. Regarding the coatings of Nb 2 O 5 , corrosion resistance increases due to higher impedance values explained by the formation of a stable structure that blocks the electrolyte penetration [25,26]. Comparing the values of Tables 2 and 3 corresponding to polarization resistance, it can be observed that the results are quite similar with both techniques (EIS and potentiodynamic polarization), and from this, the titaniumbased coating is the one with the highest resistance against corrosion degradation among the other systems.…”

Section: Electrochemical Analysismentioning

confidence: 75%

Tribocorrosion Evaluation of Nb2O5, TiO2, and Nb2O5 + TiO2 Coatings for Medical Applications

2021

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Materials used in biomedicine for purposes of long-time stay inside the body presents diverse sort of problems like cytotoxicity, wear, biocompatibility, and ion liberation along time. This paper presents the characterization of corrosion-wear combined phenomena on Nb2O5, TiO2, and Nb2O5 + TiO2 coatings with future applications as biomaterials. After the films’ production process using magnetron sputtering technique, they were characterized through an optic, scanning electron, and atomic force microscopy to evaluate their morphology, structure, and surface damage suffered by the synergy between wear and corrosion phenomena. The life in service of the implant was evaluated in terms of the coating behavior against inside body conditions like charge, wear, and electrochemical degradation. This test was made with electrochemical measurements in simulated biological fluid combined with the wear characterization implementing a potentiostat and a tribometer in a linear wear configuration with a bone pin. As a result, the different electrochemical responses of the films were evidenced by polarization curves and equivalent circuits of the systems. The coefficient of friction and surface degradation were also obtained and evaluated. Comparing the properties of the systems, we conclude that TiO2 coatings have better behavior in terms of the wear-corrosion synergy phenomena while the systems with Nb present pitting corrosion.

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“…Therefore, TiO 2 & TiN 800 °C/SUS304 has the slowest rate of corrosion as it has the lowest corrosion current, and TiN 900 °C/SUS304 has a greater corrosion current than SUS304. Wang et al [ 33 ] observed that defects in TiN coatings could induce greater corrosion currents in coated materials than those of the substrate, in addition to galvanic corrosion between the coating and substrate. This further accelerates the substrate solvation and gradually increases the corrosion current densities over time.…”

Section: Resultsmentioning

confidence: 99%

Study on the Performance of Nano-Titanium Nitride-Coated Stainless Steel Electrodes in Electro-Fenton Systems

Wang

Lin

2018

Nanomaterials

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The electro-Fenton (EF) process is a type of electrochemical oxidation process; ·OH radicals are generated on the cathode using electricity and decolorize dye wastewaters. Most studies on EF systems in the past have focused on the operating parameters of this process. In recent years, the influence of electrode performance on the EF process has begun to receive more attention. In this study, direct nitridation was used to prepare titanium nitride powders, which were thereafter coated on an SUS304 stainless steel substrate. The performance of this system in the treatment of rhodamine B dye wastewaters via the EF process was investigated. The experimental methods used in this work include: (1) scanning electron microscopy (SEM); (2) X-ray diffraction (XRD); (3) electrochemical Tafel curves; (4) linear sweep voltammetry (LSV); (5) and cyclic voltammetry (CV). It was shown that high-purity TiN can be formed at nitriding temperatures above 900 °C, and the strength of the (111) crystal plane increases with the increase in nitriding temperature; the TiN coating effectively activates the reactive surface of the electrode owing to its porous structure. In terms of corrosion resistance, the corrosion potential and corrosion current of the TiN 1000 °C/SUS304 electrode were 116.94 mV and 205 nA/cm2, respectively, and the coating had a coating porosity of 0.89 × 10−7. As compared with SUS304 stainless steel, the TiN 1000 °C/SUS304 composite electrode had a significantly greater degree of corrosion resistance and exhibited higher redox activity in LSV tests. This composite electrode could achieve a decolorization rate of 49.86% after 30 min, and 94.46% after 120 min. In summary, the TiN 1000 °C/SUS304 composite electrode is very stable and has excellent decolorization efficacy in the EF process. Our findings will serve as a useful reference for future studies on EF electrodes.

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A comparative study of the corrosion performance of titanium (Ti), titanium nitride (TiN), titanium dioxide (TiO2) and nitrogen-doped titanium oxides (N–TiO2), as coatings for biomedical applications

Cited by 67 publications

References 44 publications

Evaluation of scratch resistance of nitride coatings on Ti grade 2

Evaluation of scratch resistance of nitride coatings on Ti grade 2

Tribocorrosion Evaluation of Nb2O5, TiO2, and Nb2O5 + TiO2 Coatings for Medical Applications

Study on the Performance of Nano-Titanium Nitride-Coated Stainless Steel Electrodes in Electro-Fenton Systems

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