“…It is one of the most frequently adopted LCIA methods, with footprint evaluation of both mid-point and end-point impacts. 22 Some of the significant mid-point impact categories are global warming (GW), terrestrial acidification (TA), freshwater eutrophication (FE), marine eutrophication (ME), carcinogenic human toxicity (HTc), non-carcinogenic human toxicity (HTnc), terrestrial ecotoxicity (TET), freshwater ecotoxicity (FET), and marine ecotoxicity (MET). The sludge-based fertilizers and electricity are co-generated during the BDO production from BSG.…”
Microbial production of 2,3-butanediol (BDO) has received considerable attention as a promising alternate to fossilderived BDO. In our previous work, BDO concentration >100 g/L was accumulated using brewer's spent grain (BSG) via microbial routes which was followed by techno-economic analysis of the bioprocess. In the present work, a life cycle assessment (LCA) was conducted for BDO production from the fermentation of BSG to identify the associated environmental impacts. The LCA was based on an industrial-scale biorefinery processing of 100 metric tons BSG per day modeled using ASPEN plus integrated with pinch technology, a tool for achieving maximum thermal efficiency and heat recovery from the process. For the cradle-to-gate LCA, the functional unit of 1 kg of BDO production was selected. Onehundred-year global warming potential of 7.25 kg CO 2 /kg BDO was estimated while including biogenic carbon emission. The pretreatment stage followed by the cultivation and fermentation contributed to the maximum adverse impacts. Sensitivity analysis revealed that a reduction in electricity consumption and transportation and an increase in BDO yield could reduce the adverse impacts associated with microbial BDO production.
“…It is one of the most frequently adopted LCIA methods, with footprint evaluation of both mid-point and end-point impacts. 22 Some of the significant mid-point impact categories are global warming (GW), terrestrial acidification (TA), freshwater eutrophication (FE), marine eutrophication (ME), carcinogenic human toxicity (HTc), non-carcinogenic human toxicity (HTnc), terrestrial ecotoxicity (TET), freshwater ecotoxicity (FET), and marine ecotoxicity (MET). The sludge-based fertilizers and electricity are co-generated during the BDO production from BSG.…”
Microbial production of 2,3-butanediol (BDO) has received considerable attention as a promising alternate to fossilderived BDO. In our previous work, BDO concentration >100 g/L was accumulated using brewer's spent grain (BSG) via microbial routes which was followed by techno-economic analysis of the bioprocess. In the present work, a life cycle assessment (LCA) was conducted for BDO production from the fermentation of BSG to identify the associated environmental impacts. The LCA was based on an industrial-scale biorefinery processing of 100 metric tons BSG per day modeled using ASPEN plus integrated with pinch technology, a tool for achieving maximum thermal efficiency and heat recovery from the process. For the cradle-to-gate LCA, the functional unit of 1 kg of BDO production was selected. Onehundred-year global warming potential of 7.25 kg CO 2 /kg BDO was estimated while including biogenic carbon emission. The pretreatment stage followed by the cultivation and fermentation contributed to the maximum adverse impacts. Sensitivity analysis revealed that a reduction in electricity consumption and transportation and an increase in BDO yield could reduce the adverse impacts associated with microbial BDO production.
“…The chemical composition of NCGs exemplifies substantial carbon content, the proper utilization of which is necessary for reducing the carbon footprints of the overall process. Most of the published literature suggests the combustion of NCGs to produce heat that can be either recycled back in the process for reducing the process dependence on external fossil energy sources, or credits can also be earned from the replacement of the natural gas grid generated heat, thereby reducing the process environmental impacts. ,− Furthermore, the energy produced from NCGs combustion can also be employed for running the turbine of the gas-fired powerplants to produce electricity, which can benefit the system by substituting the electricity grid mix . Besides this, conversion to biomethane through steam reforming of NCGs and production of liquid hydrocarbon fuels through Fischer–Tropsch’s synthesis include other utilization pathways that are least explored for the NCGs produced from the pyrolysis process.…”
The current study presents the life cycle analysis (LCA) of a biochar-catalyzed pyrolysis-based biorefinery system. Noncondensable gases (NCGs), produced as a coproduct, have been recycled back to the system, while biochar produced was employed for catalyst preparation, to visualize a biorefinery model. Results showed the considerable environmental impact of the process, in particular of the catalyst and energy sources utilized during the process. Matching up with the LCA metrics, both single parameter and Monte Carlo uncertainty analyses also revealed the high sensitivity of the obtained impacts for the impregnating chemical (i.e., ZnCl 2 , H 3 PO 4 , and NaOH) employed during catalyst preparation. Among different processes, the Ni/BC-H 3 PO 4 catalyzed process with NCG recycling has emerged as the best possible case with the lowest environmental emissions (GWP ≈ 0.109 kg CO 2 equivalent) and low cumulative energy demand (∼2.47 MJ) together with high process efficacy and productivity. Furthermore, sustaining process energy needs with varieties of different sources advocates for renewable sources (more specifically hydropower) over nonrenewable sources of energy. The study highlights the hotspots of the current technology, envisaging ways of reducing emissions through clean/renewable energy sources as well as utilizing less impact-causing intermediate materials, and thus, acting like a building stone in creating a base toward the vision of achieving net zero emissions.
“…This trade-off requires further analysis and discussion for the development of the biofuel market. Analytical methods like environmental sustainability assessment related to bioethanol production have been carried out for some agricultural residues as feedstocks in different countries and under different conditions [ 1 , 3 , [9] , [10] , [11] ]. This methodology is also recognized as a standardized tool whose main objective to analyze and quantifyof the environmental impacts associated with a product by quantifying emissions and discharges that could affect the environment [ 11 ].…”
Section: Introductionmentioning
confidence: 99%
“…Analytical methods like environmental sustainability assessment related to bioethanol production have been carried out for some agricultural residues as feedstocks in different countries and under different conditions [ 1 , 3 , [9] , [10] , [11] ]. This methodology is also recognized as a standardized tool whose main objective to analyze and quantifyof the environmental impacts associated with a product by quantifying emissions and discharges that could affect the environment [ 11 ]. Previous studies were carried out with the aim of evaluating the environmental burdens of bioethanol production from different biomasses [ [11] , [12] , [13] , [14] ].…”
Section: Introductionmentioning
confidence: 99%
“…This methodology is also recognized as a standardized tool whose main objective to analyze and quantifyof the environmental impacts associated with a product by quantifying emissions and discharges that could affect the environment [ 11 ]. Previous studies were carried out with the aim of evaluating the environmental burdens of bioethanol production from different biomasses [ [11] , [12] , [13] , [14] ]. However, the analysis of emissions resulting from the production of bioethanol still remains a subject of debate and concern since the limits of the system vary according to researchers, thus causing variability in the results [ 15 ].…”
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