A comparative analysis of the description of adsorptional equilibria given by osmotic adsorption theory and the theory of micropore volume filling

On the Nature of the Heterogeneity of Real Solid Surfaces

“…22 compares the adsorption energy distributions, calculated by assuming Langmuir and Jovanovic isotherms as the kernel ('local' ) isotherm, in the integral equation 6.6.28. The form of the energy distributions remains unchanged on changing the local isotherm.…”

“…22. Comparison of the adsorption energy distributions (equation 6.6.29) calculated from experimental adsorption isotherms by taking the Langmuir equation as the 'local' isotherm, (--------) and Jovanovic 'local' isotherm (----------).…”