“…15 In modern photonic technology, doping at, for example, the cation site, is widely used for tuning the structural, linear and nonlinear optical, ferroelectric and other physical property of functional crystals. [16][17][18] One doping element, as a rule, is applied to doping and the expected solid solution property can be speculated over the solubility range by different empirical relations. When two doping elements with different ion charge and radius are taken, the situation becomes more complicated and the solid solution behavior is less predictable, because, in many cases, the doping ion distribution over the crystallographic sites and the defect formation mechanism is unclear.…”