The machinability of hard-to-cut CoCr alloys manufactured by Selective Laser Melting (SLM) technology is not yet sufficiently studied. Therefore, this work focuses on evaluation of surface texture formation during face turning of CoCr alloy. As part of the research, two specimen types were subject to comparison: made with the application of conventional casting and manufactured by additive manufacturing—SLM. A number of analytical and experimental methods were employed to describe the specimen composition and morphology, as: X-Ray Diffraction Analysis (XRD), optical metallurgical microscopy, confocal optical microscopy, and Vickers hardness HV0.1 measurements. In the next stage, the measurements of surface topographies formed during turning in a range of variable cutting speeds and feeds were carried out. Ultimately the multi-factor MANOVA (Multivariate Analysis of Variance) illustrating the influence of manufacturing technology, cutting speed, and feed ratio on selected surface parameters of samples was made. It has been demonstrated that during face turning with feeds up to 0.15 mm/rev, the similar values of surface roughness height and material ratio curve parameters were reached for both tested CoCr alloys. However, in a range of higher feed values, the surface quality of CoCr samples fabricated by SLM was lower than that reached for CoCr after casting process.