1963
DOI: 10.1021/ac60206a011
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A Combustion-Gas Chromatographic Method for the Simultaneous Determination of Carbon and Sulfur in Ferrous Metals.

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1965
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Cited by 19 publications
(3 citation statements)
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“…Carbon analyses continue to be made by direct oxidation at high temperature; chromatographic methods and equipment for measuring the evolved carbon dioxide have come into widespread use in the past two years (133,206,226) and probably are second only to the vacuum emission direct reading spectrograph for this purpose. Thermal conductivity (127), infrared (217), and conductometric methods (175) are used to a lesser extent.…”
Section: Carbonmentioning
confidence: 99%
“…Carbon analyses continue to be made by direct oxidation at high temperature; chromatographic methods and equipment for measuring the evolved carbon dioxide have come into widespread use in the past two years (133,206,226) and probably are second only to the vacuum emission direct reading spectrograph for this purpose. Thermal conductivity (127), infrared (217), and conductometric methods (175) are used to a lesser extent.…”
Section: Carbonmentioning
confidence: 99%
“…In subsequent papers, we were able to show a maximum detector sensitivity of approximately 5 p.p.m. carbon under ideal parameter conditions using gas chromatography (2) and combustion-gas chromatography (S).…”
Section: Franci L Anderson Evan H Appelmanmentioning
confidence: 99%
“…One difficulty in their use is the need to introduce plug samples of gas into the chromatograph. Previous methods for achieving this involved collecting the oxidation products in liquid nitrogen traps (1-3) or on solid absorbents (4-7), or the use of rapid oxidation methods, e.g., high frequency induction furnaces (8)(9)(10)(11) or direct injection of liquid samples onto heated oxidants (12-15). These methods either add considerably to the analysis time, or to the cost of the equipment, or are unsuitable for fertilizer materials in which the carbonaceous matter can be largely water insoluble.…”
mentioning
confidence: 99%