2011
DOI: 10.1016/j.proeng.2011.12.328
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A colorimetric CO sensor for fire detection

Abstract: We report on a colorimetric carbon monoxide (CO) sensor based on a rhodium complex. The sensor relies on changes in the light absorption properties of the chemochromic reagent when exposed to the gas. Its optical properties in solution and in a polymeric matrix were investigated by spectrophotometry. A strong color change from purple to yellow was obtained when exposed to CO. For its implementation in a sensor configuration, the complex embedded in a PVC-based matrix was spin-coated onto a glass waveguide. The… Show more

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Cited by 18 publications
(12 citation statements)
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“…Sensing experiments were carried out in a stainless steel cylindrical custom-built gas-sensing chamber, with the following dimensions: internal diameter 21.05 cm, internal depth 9.25 cm, internal volume 3219 cm 3 . Ammonia gas (500 ppm, nitrogen fill) and N 2 gas (for further dilution of NH 3 ) were purchased from BOC gases UK.…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…Sensing experiments were carried out in a stainless steel cylindrical custom-built gas-sensing chamber, with the following dimensions: internal diameter 21.05 cm, internal depth 9.25 cm, internal volume 3219 cm 3 . Ammonia gas (500 ppm, nitrogen fill) and N 2 gas (for further dilution of NH 3 ) were purchased from BOC gases UK.…”
Section: Methodsmentioning
confidence: 99%
“…2 For example, the cheapest and thus a popular type of CO detector utilises colorimetric changes in a chemical layer, triggering an alarm if a colour change occurs. 3 The fact that this type of CO detector is relatively cheap is an anomaly compared to most commercially available, low concentration detection systems.…”
Section: Introductionmentioning
confidence: 99%
“…− Sensors Fabricated with Transition Metal Complexes Transition metal complexes, such as iron pincer complexes [63], rhodium complexes [38,[64][65][66], and rhenium-iridium complexes [67], exhibit significant color changes sensible to naked eyes when they are exposed to CO. The color change is believed to be the result of the formation of CO coordinates by replacing the weakly bound donor ligands of the complexes with CO molecules [64,65,67]. Compared with the previous two types of optical CO sensing materials, transition metal complexes can detect CO under room temperature with measurement results sensible to human eyes [38,63,64].…”
Section: Colorimetric Sensorsmentioning
confidence: 99%
“…Finally, Courbat et al developed a colorimetric CO sensor based on a rhodium complex [ 88 ]. The sensor relied on the chemochromic properties of the reagent when exposed to CO: its color changed from purple to yellow when CO concentration level increases.…”
Section: Fire Detectors Exclusively Based On Chemical Sensingmentioning
confidence: 99%