Loss of fenitrothion from post-harvest application to wheat, oats, paddy rice and sorghum followed a second-order rate process, with rate of loss being proportional, at a fixed temperature, to the amount of fenitrothion and the activity of water, which was obtained from the equilibrium partial pressure of water vapour. The effect of temperature on loss was of the form of the Arrhenius equation. A chart relating halflife to temperature and relative humidity is presented in a form suitable for field use, and a mechanism is proposed for loss of fenitrothion.