Abstract:A luminescent Cobalt(II) co-crystal [Co13(PDC)16(H2O)24.7H2O] 1 (where H2PDC = 2,6pyridinedicarboxylic acid) have been prepared by oven-heating and slow evaporation of solvent. Single crystal X-ray diffraction (SCXRD) analysis revealed that 1 is a mixture of complexes that crystallizes in the triclinic space group P-1 and the geometry around the Co(II) ions is octahedral. The structure is extensively imbued with hydrogen bonding that helps in stabilizing the complex. Thermogravimetric analysis indicates that 1… Show more
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