“…As thermosetting polymers with broad application prospects, − epoxy polymers (EPs) have attracted extensive attention for their superior mechanical properties brought about by three-dimensional crosslinked structures. Compared with phenol-formaldehyde resins and polyethylene, EPs have the potential for possessing high moduli, , high strength, − and high toughness, − which is more suitable for the preparation of high-performance composites. , Various approaches have been adopted to elevate the performance of EPs to meet increasing requirements. , However, designing crosslinked polymers with the combination of high modulus, high strength, and high toughness is still a long-term and arduous challenge due to many influencing factors, such as molecular stiffness, intermolecular forces, and chain packing. , These factors usually intricately affect each other, resulting in intrinsically conflicting mechanical properties in the design. As such, it is imperative to design novel EPs with high moduli, high strength, and high toughness from a more intuitive point of view.…”