A Cascade C(sp3)−H Annulation Involving C(alkyl),C(alkyl)‐Palladacycle Intermediates
Liwei Zhou,
Xiahong Chen,
Qiong Peng
et al.
Abstract:C−H bond functionalization involving C,C‐palladacycle intermediates provides a unique platform for developing novel reactions. However, the vast majority of studies have been limited to the transformations of C(aryl),C‐palladacycles. In sharp contrast, catalytic reactions involving C(alkyl),C(alkyl)‐palladacycles have rarely been reported. Herein, we disclose an unprecedented cascade C(sp3)−H annulation involving C(alkyl),C(alkyl)‐palladacycles. In this protocol, alkene‐tethered cycloalkenyl bromides undergo i… Show more
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