Articles you may be interested in Effect of surface modification by self-assembled monolayer on the ZnO film ultraviolet sensor Orientational self-assembled field-effect transistors based on a single-walled carbon nanotubeThe authors report pH-dependent conductance behaviors of single-walled carbon nanotube ͑SWCNT͒ multilayer thin-film sensors. SWCNTs are functionalized with carboxylic groups, and layer-by-layer assembled alternatively with polycation, polydiallyldimethyammonium chloride on the microfabricated metal electrodes. Current-voltage ͑I-V͒ characteristics show that the conductance of SWCNT multilayer thin-film sensors decreases with increase of pH values. On the other hand, the multilayer resistors with polymethylmethacrylate ͑PMMA͒ as a passivation layer demonstrate the increasing conductance with pH, opposite to the case of the absence of PMMA layer. The conductance change in the absence of PMMA attributes to doping/undoping of holes as charge carriers by molecular protonation/deprotonation of p-type semiconducting SWCNTs. With PMMA layer, concentration gradient of hydrogen ions on the dielectric forms the gate bias voltage, which changes the conductance of underlying semiconducting SWCNT layer. Each pH-dependent behavior has versatile applications for chemical and biological detections.