Seismic observations show a reduced compressional-wave velocity gradient at the base of the outer core relative to the preliminary reference Earth model and seismic wave asymmetry between the east-west hemispheres at the top of the inner core. Here we propose a model for the inner core boundary (ICB), where a slurry layer forms through fractional crystallization of an Fe alloy at the base of the outer core (F layer) above a compacting cumulate pile at the top of the inner core (F′ layer). Using recent mineral physics data, we show that fractional crystallization of an Fe alloy (e.g., Fe-Si-O) with a solid fraction of~15 ± 5% and preferential light element partitioning into the liquid can explain the observed reduced velocity gradient in the F layer. The compacting cumulate pile in the F′ layer may exhibit lateral variations in thickness between the east-west hemispheres due to lateral variations of large-scale heat flux in the outer core, which may explain the east-west asymmetry observed in the seismic velocity. Our model suggests that the inner core solid has a high shear viscosity >10 22 Pa/s.
Plain Language Summary Seismic observations show a reduced P wave velocity gradient layerat the bottom~280 km of the outer core and a hemispherical dichotomy at the top~50-200 km of the inner core compared to the one-dimensional Preliminary reference Earth model (PREM). These seismic features manifest physical and chemical phenomena linked to thermal evolution and formation processes of the inner core. We have developed a physical model to explain these seismic features. At the inner-outer boundary, the crystallization of Fe alloy co-exists with the residue melt producing a "snowing" slurry layer (F layer), consistent with observed seismic velocity gradient. Solid Fe alloy crystals accumulate and eventually compact at the top of the inner core, and may exhibit lateral variations in thickness between the east-west hemispheres. Our model can explain the east-west asymmetry observed in the seismic velocity. Our model uses mineral physics and seismological results to provide a holistic view of the physical and chemical processes for the inner-core growth over geological time.