Abstract:A new 3D manganese(II) coordination polymer, formulated as [Mn3(HL)6] (1) (where H2L = 6-hydroxypicolinic acid), has been hydrothermally synthesized and characterized by single-crystal X-ray crystallographic analysis along with other spectroscopic and magnetic techniques. Structural analysis shows that the compound crystallizes in the monoclinic C2/c space group and is a non-porous 3D coordination polymer formed by three different Mn(II) centres connected by 6-hydroxypicolinic acid ligands in their keto form. … Show more
“…This phenomenon has been observed in compounds with different dimensionalities and metallic centres. [23][24][25][26] Here we report the magnetic properties of two In both cases there are important intermolecular interactions that give rise to long-range canted antiferromagnetic orderings at low temperatures. These complexes illustrate the important role of intermolecular interactions in the magnetic properties of monomeric complexes.…”
Section: Introductionmentioning
confidence: 96%
“…This phenomenon has been observed in compounds with different dimensionalities and metallic centres. 23–26…”
Section: Introductionmentioning
confidence: 99%
“…= m 2 /2h, m = −c) 4 25. 5.08 in-plane is called s-bond and the out-of-plane is p-bond contribution.…”
“…This phenomenon has been observed in compounds with different dimensionalities and metallic centres. [23][24][25][26] Here we report the magnetic properties of two In both cases there are important intermolecular interactions that give rise to long-range canted antiferromagnetic orderings at low temperatures. These complexes illustrate the important role of intermolecular interactions in the magnetic properties of monomeric complexes.…”
Section: Introductionmentioning
confidence: 96%
“…This phenomenon has been observed in compounds with different dimensionalities and metallic centres. 23–26…”
Section: Introductionmentioning
confidence: 99%
“…= m 2 /2h, m = −c) 4 25. 5.08 in-plane is called s-bond and the out-of-plane is p-bond contribution.…”
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