A 3D chiral Zn(II) complex based on achiral ligands 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole and adipate

Two new Cd(II) complexes, {[Cd(COO) 2 ] 2 Á2H 2 O} n (1) and {[CdCl(COO) 2 (Hbmi)]ÁH 2 O} n (2), were obtained through the reactions of oxalic acid (H 2 ox) with CdCl 2 Á2.5H 2 O in the presence of 1-[(benzoimidazol-yl) methyl]-1H-tetrazole (bmt) or 1-[(benzoimidazol-yl)methyl]-1H-imidazol (bmi). Single-crystal X-ray diffraction shows that complex 1 has a 3-D structure with the topological notation of (4 8 Á 62 )(4 6 Á 6 6 Á 8 3 )(4 2 Á 8 4 ), in which the oxalate displays two kinds of coordination modes: formation of the layers (μ 6 -ox) and linking the layers (μ 4 -ox). In complex 2, oxalates bridge Cd(II) ions, forming a 1-D chain, and (Hbmi) + cations coordinate to the Cd(II) ions in monodentate mode and hang at two sides of the main chain. This indicates that subtle modification of the N-donor ligands can result in complexes with different compositions and architectures. Moreover, their IR spectra, PXRD (powder X-ray diffraction) patterns, thermogravimetric analyses, and fluorescence properties are also investigated.

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Syntheses and Characterizations of Two New Cadmium Complexes Based on Oxalate

Miao

Cheng

Liang

et al. 2015

Bulletin Korean Chem Soc

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New bioactive Co (II) coordination polymers with morphline and carboxylate ligands; Synthesis, structures, spectroscopic and thermal properties

Mukred¹,

Yehya²,

Al-Gabr³

et al. 2022

J Polym Res

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Two chiral coordination polymers constructed from (1R,2R)-1,2-diaminocyclohexane derivative: Syntheses, structures and properties

Xue

Zhang

Sheng

et al. 2015

Inorganic Chemistry Communications

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A 3D chiral Zn(II) complex based on achiral ligands 2-(1H-imidazolyl-1-methyl)-1H-benzimidazole and adipate

Cited by 13 publications

References 30 publications

Syntheses and Characterizations of Two New Cadmium Complexes Based on Oxalate

Syntheses and Characterizations of Two New Cadmium Complexes Based on Oxalate

New bioactive Co (II) coordination polymers with morphline and carboxylate ligands; Synthesis, structures, spectroscopic and thermal properties

Two chiral coordination polymers constructed from (1R,2R)-1,2-diaminocyclohexane derivative: Syntheses, structures and properties

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