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Ezerskaya, N. A.; Toropchenova, E. S.; Кубракова, И. В.; Krasheninnikova, S. V.; Kudinova, T. F.; Fomina, T. A.; Kiseleva, I. N.

doi:10.1023/a:1026602717639

Cited by 5 publications

(1 citation statement)

References 7 publications

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“…Both the temperature and the reaction time increased the yield, too; however, in these cases, temperatures >140 • C and heating time above 10 min were detrimental to the yield, probably due to some decomposition. Under the optimal conditions, the yield was close to 100%, whereas for CH, it was no higher than 75% [154].…”

Section: Rhodiummentioning

confidence: 85%

Microwave-Assisted Synthesis: Can Transition Metal Complexes Take Advantage of This “Green” Method?

Gabano

Ravera

2022

Molecules

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Microwave-assisted synthesis is considered environmental-friendly and, therefore, in agreement with the principles of green chemistry. This form of energy has been employed extensively and successfully in organic synthesis also in the case of metal-catalyzed synthetic procedures. However, it has been less widely exploited in the synthesis of metal complexes. As microwave irradiation has been proving its utility as both a time-saving procedure and an alternative way to carry on tricky transformations, its use can help inorganic chemists, too. This review focuses on the use of microwave irradiation in the preparation of transition metal complexes and organometallic compounds and also includes new, unpublished results. The syntheses of the compounds are described following the group of the periodic table to which the contained metal belongs. A general overview of the results from over 150 papers points out that microwaves can be a useful synthetic tool for inorganic chemists, reducing dramatically the reaction times with respect to traditional heating. This is often accompanied by a more limited risk of decomposition of reagents or products by an increase in yield, purity, and (sometimes) selectivity. In any case, thermal control is operative, whereas nonthermal or specific microwave effects seem to be absent.

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Section: Rhodiummentioning

confidence: 85%