Untitled

Golub, A. S.; Zubavichus, Ya. V.; Лененко, Н. Д.; Slovokhotov, Yu.L.; Danot, M.; Novikov, Yu. N.

doi:10.1023/a:1015058823903

Cited by 13 publications

(10 citation statements)

References 23 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…As might be expected from the ionic mechanism of the reaction (5), the content of the intercalated cations in precipitated products depends on the negative charge retained on the layers at the moment of formation of a given compound as well as on the geometrical sizes of the cations (more precisely, on the minimum matrix layer area occupied by the corresponding cation). As was shown for the series of compounds (R 4 N) x MoS 2 , 115,127 this charge can reach * 0.3 " e per Mo atom for the intercalation of Me 4 N + or RMe 3 N + cations, which form closely packed monolayers between the neighbouring MoS 2 layers. In this case, the long-chain n-alkyl substituents R in RMe 3 N + are oriented perpendicular to the MoS 2 layers (Fig.…”

Section: O2mentioning

confidence: 74%

Single-layer dispersions of transition metal dichalcogenides in the synthesis of intercalation compounds

Golub¹,

Zubavichus²,

Slovokhotov³

et al. 2003

Russ. Chem. Rev.

View full text Add to dashboard Cite

Chemical methods for the exfoliation of transition metal Chemical methods for the exfoliation of transition metal dichalcogenides in a liquid medium to give single-layer dispersions dichalcogenides in a liquid medium to give single-layer dispersions containing quasi-two-dimensional layers of these compounds are containing quasi-two-dimensional layers of these compounds are surveyed. Data on the structure of dispersions and their use in the surveyed. Data on the structure of dispersions and their use in the synthesis of various types of heterolayered intercalation com-synthesis of various types of heterolayered intercalation compounds are discussed and described systematically. Structural pounds are discussed and described systematically. Structural features, the electronic structure and the physicochemical proper-features, the electronic structure and the physicochemical properties of the resulting intercalation compounds are considered. The ties of the resulting intercalation compounds are considered. The potential of this method of synthesis is compared with that of potential of this method of synthesis is compared with that of traditional solid-state methods for the intercalation of layered traditional solid-state methods for the intercalation of layered crystals. The bibliography includes 192 references crystals. The bibliography includes 192 references. .

show abstract

Section: O2mentioning

confidence: 74%

Single-layer dispersions of transition metal dichalcogenides in the synthesis of intercalation compounds

Golub¹,

Zubavichus²,

Slovokhotov³

et al. 2003

Russ. Chem. Rev.

View full text Add to dashboard Cite

show abstract

“…It is worth noting that solvothermal treatment can accelerate the intercalation process as compared with the room temperature intercalation process, which needs about 1-7 days. [34][35][36] Subsequently, the exfoliation process was performed in the presence of commercially available thiol reagents such as MPA, CY and TG, affording MoS 2 -MPA, MoS 2 -CY and MoS 2 -TG, respectively. The exfoliation process leads to deformation of MoS 2 's crystal structure and formation of numerous internal edges and defects.…”

Section: Synthesis and Characterization Of Organic Functional Groups ...mentioning

confidence: 99%

Facile approach to surface functionalized MoS₂nanosheets

et al. 2014

View full text Add to dashboard Cite

Two-dimensional layered MoS 2 nanosheets exhibit a wide range of attractive properties and hold great promise in myriad fields. However, the poor performance of surface functionality greatly limits their applications. In this paper, we report on a facile approach to direct synthesis of organic functional group decorated MoS 2 (OFGD-MoS 2 ) nanosheets based on the simultaneous exfoliation of bulk MoS 2 crystals and chemical conjugation of thiol ligands. The morphology and structure of OFGD-MoS 2 nanosheets are systematically characterized using microscopy (TEM, SEM, AFM), thermal gravimetric analysis (TGA), and spectroscopy (Raman, FTIR, XPS) measurements. The content of attached functional groups can be controlled simply by changing the experimental conditions. Furthermore, the introduced functional groups show excellent structural stability and high chemical reactivity, making them promising for further modification as confirmed by the in situ growth of inorganic nanoparticles and polymers. In addition, surface functionalized WS 2 nanosheets can also be synthesized by this approach. This investigation paves the way for the synthesis and applications of advanced MoS 2 -based materials.

show abstract

“…In the presence of positively charged guest species, the MoS 2 host layers will be restacked and result in the formation of novel intercalation materials. 10 Employing this single-layer dispersion technique, MoS 2 has been intercalated with a variety of compounds, such as conducting polymers, 2,12 small organic molecules, 3,13 and inorganic Co 6 Q 8 (PR 3 ) (Q ~S, Se, Te, R ~alkyl) clusters. 14 Compared with these compounds, little work has been reported on intercalating metal coordination complexes into the host MoS 2 layers with the exception of [Ru(arene)(H 2 O)] 2115 and [Fe(porphyrin)] 31 .…”

Section: Introductionmentioning

confidence: 99%

Preparation and characterization of nanocomposite materials consisting of molybdenum disulfide and cobalt(ii) coordination complexes

et al. 2004

View full text Add to dashboard Cite

Untitled

Cited by 13 publications

References 23 publications

Single-layer dispersions of transition metal dichalcogenides in the synthesis of intercalation compounds

Single-layer dispersions of transition metal dichalcogenides in the synthesis of intercalation compounds

Facile approach to surface functionalized MoS₂nanosheets

Preparation and characterization of nanocomposite materials consisting of molybdenum disulfide and cobalt(ii) coordination complexes

Contact Info

Product

Resources

About

Untitled

Cited by 13 publications

References 23 publications

Single-layer dispersions of transition metal dichalcogenides in the synthesis of intercalation compounds

Single-layer dispersions of transition metal dichalcogenides in the synthesis of intercalation compounds

Facile approach to surface functionalized MoS2nanosheets

Preparation and characterization of nanocomposite materials consisting of molybdenum disulfide and cobalt(ii) coordination complexes

Contact Info

Product

Resources

About

Facile approach to surface functionalized MoS₂nanosheets