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Gorshkov, A. B.

doi:10.1023/a:1018887912250

Cited by 6 publications

(2 citation statements)

References 6 publications

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“…However, in most cases, a large excess of these compounds (e.g., 20–100 equiv relative to the platinum catalyst) is required to achieve a moderate latency and sometimes the controllability is still not sufficient. In addition, although it is possible to control the activity and further increase the pot‐life to any desired extent by selecting inhibitor species and amount, an adverse effect on the cross‐linking behavior, for example, impairing the shear strength of the cured silicone formulations, is unavoidably associated with increasing shelf life …”

Section: Curing Systems (Cross‐linking Reactions)mentioning

confidence: 99%

Catalytic Systems for the Cross‐Linking of Organosilicon Polymers

Wang

Klein

Mejía

2017

Chemistry An Asian Journal

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Silicones and silicone rubbers are omnipresent in household and industrial products such as lubricants,c oatings, sealants,i nsulators, medicald evices, etc. This plethora of applicationsa rises from their unparalleled properties including hydrophobicity,l ow surfacee nergy,c hemical inertness, extreme temperature stability,e lasticity,a nd biocompatibility.E vent hough silicones have been known for more than five decades, their chemistry is still far from fully understood. Industrially,t he vast majority of processesf or their synthesis, transformation, andu se are based on rather well established, alas outdated technologies, which are frequently empirical and poorly investigated. Thisr eview attempts to summarize the different approaches for the synthesis of silicone rubbers by vulcanizationorc uring of silicone polymers, the catalysts used, and the corresponding reaction mechanisms. Apart from the well-known methods (radical, hydrosilylation, and metal-based condensation), novel approaches such as organo-and bio-catalysis are also addressed.

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Section: Curing Systems (Cross‐linking Reactions)mentioning

confidence: 99%

Catalytic Systems for the Cross‐Linking of Organosilicon Polymers

Wang

Klein

Mejía

2017

Chemistry An Asian Journal

View full text Add to dashboard Cite

show abstract

“…Last years the development of numerical methods on the one hand and permanent extension of computational possibilities on the other has opened ways to solution of complicated problems in this field. The flow round cylinder was studied on the base of Navier-Stokes [3,4] and Reynolds equations [5]. In [6] the approbation of potential in the model of variable soft sphere for nitrogen was performed by comparison of results of the direct simulation Monte Carlo (DSMC) method [7] with experiment.…”

Section: Introductionmentioning

confidence: 99%