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Acidic‐basic interactions in tungstate melts based on tungsten electroplating out of them

“…In order to calculate ΔG T we used the literature values of thermodynamical magnitudes of the considered compounds . In case of the absence of information about the temperature dependences of heat capacity in the methodology of calculations in and reference data were used .…”

High-temperature electrochemical synthesis of carbon-containing inorganic compounds under excessive carbon dioxide pressure

“…To this end, electrochemical species of refractory metal of different composition and structure, which are discharged at the potential of carbon deposition from CO 2 , have been formed in the melt by means of acid-base interactions. References [12,13] showed the possibility of effecting electrochemical co-reduction of carbon dioxide and different ionic forms of molybdenum and tungsten (cationized…”

Current problems of the electrochemistry of titanium and boron. Synthesis of titanium diboride and titanium intermetallic compounds in ionic melts

“…The advantages of this method are relative simplicity of the equipment, the ready accessibility of the initial compounds, the possibility of preparing simple or complex composite coatings of high-melting compounds, the relatively low temperature of the process, and the possibility of controlling the morphology and the composition of the cathodic deposit by varying the electrolysis parameters. The theoretical grounds of this method have been described in detail, 48 and examples of its practical implementation can be found in reviews. 49,50 Depending on the nature of the electrolyte used, two variants of electrochemical synthesis of titanium diboride can be distinguished, namely, syntheses from oxygen-containing systems and from halide systems.…”