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Cited by 28 publications
(16 citation statements)
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“…Among them, the TNT array photoanode presents several advantages for the production of molecular hydrogen. For example, (1) due to light scattering within a porous structure, incident photons are more effectively absorbed than on a flat electrode; (2) the tubular nanoarchitecture results in a large effective surface area in close proximity with the electrolyte, thus enabling diffusive transport of photogenerated holes to oxidizable species in the electrolyte; (3) the relevant structure sizes of the TNT arrays, i.e., half the wall thickness, are about 20 nm, which is less than the retrieval length of crystalline TiO 2 [122], hence bulk recombination is greatly reduced and the quantum yield enhances.…”
Section: Water Splitting To Produce Hydrogenmentioning
confidence: 99%
“…Among them, the TNT array photoanode presents several advantages for the production of molecular hydrogen. For example, (1) due to light scattering within a porous structure, incident photons are more effectively absorbed than on a flat electrode; (2) the tubular nanoarchitecture results in a large effective surface area in close proximity with the electrolyte, thus enabling diffusive transport of photogenerated holes to oxidizable species in the electrolyte; (3) the relevant structure sizes of the TNT arrays, i.e., half the wall thickness, are about 20 nm, which is less than the retrieval length of crystalline TiO 2 [122], hence bulk recombination is greatly reduced and the quantum yield enhances.…”
Section: Water Splitting To Produce Hydrogenmentioning
confidence: 99%
“…A material can be an efficient photo catalyst if its structure is so organized as to minimize the possibility of recombining the photo generated hole-electron pair. Because the hole recombination length in TiO2 is about 100 nm, the optimal architecture must be a nano-structured material [1]. Consequently, many works have focused on the preparation of TiO 2 nano-rods [2,3], nanowires [4,5] and nanotubes [6].…”
Section: Introductionmentioning
confidence: 99%
“…The latter trigger reactive radical species with concentration proportional to water-dissolved oxygen [1] giving TiO 2 nanostructures photo-catalytic and ionexchange abilities, [2][3][4] and thus great technological interest for applications such as photo-catalysis, self-cleaning surfaces, and biomaterials [5][6][7]. In order to optimize the narrow UV-absorption gap of TiO 2 to enable excitation under visual part of solar spectrum and thus to improve their photo-catalytic behavior, different modification strategies have been studied over recent years using various electron-donating ligands, mainly organic or rarely inorganic molecules absorbing light within the visible region [8][9][10].…”
Section: Introductionmentioning
confidence: 99%