“…The aqueous solution prepared from the solid glucuronic acid sodium salt had an unadjusted pH of 6, and the C NMR spectrum in solution (Fig. (b)) is similar to the spectrum reported in the literature for glucuronic acid sodium salt in D 2 O . The spectrum contains 12 peaks, six for each of the α and β anomers of the glucuronic acid monomer, which form by the mutarotation process that takes place in aqueous solution.…”
Section: Resultssupporting
confidence: 68%
“…The peak intensities are similar for both anomers. The assignment of the peaks is done based on literature reported values; thus the peaks at 178.1 ppm and 177.1 ppm represent the carboxylate group at the C6 atom, and the peaks at 97.2 ppm and 93.4 ppm are assigned to the C1 carbon atoms for the β anomer and for the α anomer, respectively (see Figs (a) and (b) for carbon numbers). The other grouped peaks in the region 70–80 ppm correspond to the resonances of the ring carbon atoms C2–C5 …”
Polyglucuronic acids provide a biocompatible matrix for industries ranging from pharmaceuticals to agriculture. Here we provide a method for selectively producing α‐polyglucuronic acid, a simple alternative to the oxidation of cellulose or amylose with 2,2,6,6‐tetramethylpiperidine‐1‐oxyl radical (TEMPO) or isolation from bacterial cultures. Atomic force micrographs show the pH‐dependent formation and persistence of polyglucuronic acid fibrils, while NMR studies demonstrate the selectivity of the glycosidic linkage. By controlling pH, oligoglucuronate chains are created, with both NMR and AFM data showing the preservation of this linkage in basic medium after formation under acid. Clear evidence for the formation of the C–O–C glycosidic bond comes from peaks in the 13C NMR spectra, revealing a linkage through the anomeric carbon atom and also a linkage with a ring carbon atom.
“…The aqueous solution prepared from the solid glucuronic acid sodium salt had an unadjusted pH of 6, and the C NMR spectrum in solution (Fig. (b)) is similar to the spectrum reported in the literature for glucuronic acid sodium salt in D 2 O . The spectrum contains 12 peaks, six for each of the α and β anomers of the glucuronic acid monomer, which form by the mutarotation process that takes place in aqueous solution.…”
Section: Resultssupporting
confidence: 68%
“…The peak intensities are similar for both anomers. The assignment of the peaks is done based on literature reported values; thus the peaks at 178.1 ppm and 177.1 ppm represent the carboxylate group at the C6 atom, and the peaks at 97.2 ppm and 93.4 ppm are assigned to the C1 carbon atoms for the β anomer and for the α anomer, respectively (see Figs (a) and (b) for carbon numbers). The other grouped peaks in the region 70–80 ppm correspond to the resonances of the ring carbon atoms C2–C5 …”
Polyglucuronic acids provide a biocompatible matrix for industries ranging from pharmaceuticals to agriculture. Here we provide a method for selectively producing α‐polyglucuronic acid, a simple alternative to the oxidation of cellulose or amylose with 2,2,6,6‐tetramethylpiperidine‐1‐oxyl radical (TEMPO) or isolation from bacterial cultures. Atomic force micrographs show the pH‐dependent formation and persistence of polyglucuronic acid fibrils, while NMR studies demonstrate the selectivity of the glycosidic linkage. By controlling pH, oligoglucuronate chains are created, with both NMR and AFM data showing the preservation of this linkage in basic medium after formation under acid. Clear evidence for the formation of the C–O–C glycosidic bond comes from peaks in the 13C NMR spectra, revealing a linkage through the anomeric carbon atom and also a linkage with a ring carbon atom.
“…The above-mentioned warp resonant instability can be interpreted as a particular case of a more general resonant instability (Kato 2013(Kato , 2014. The latter instability is called here and hereafter "wave-wave resonant instability in deformed disks".…”
mentioning
confidence: 99%
“…The latter instability is called here and hereafter "wave-wave resonant instability in deformed disks". The instability condition can be expressed in a quite simple form (Kato 2013). For this resonant instability to work, the disk deformation required is not restricted only to a warp (and eccentric deformation), but also other types of disk deformations are allowed, if there are disk oscillation modes which satisfy necessary instability conditions.…”
A possible origin of kHz QPOs in low-mass X-ray binaries is proposed. Recent numerical MHD simulations of accretion disks with turbulent magnetic fields of MRI definitely show the presence of two-armed spiral structure in quasi-steady state of accretion disks. In such deformed disks, two-armed (m = 2) c-mode (n = 1) oscillations are excited by wave-wave resonant instability. Among these excited oscillations, the fundamental in the radial direction (n r = 0) will be the higher kHz QPO of a twin QPOs, and the first overtone (n r = 1) in the radial direction will be the lower kHz QPO of the twin. A possible cause of the twin high-frequency QPOs (HFQPOs) in BH X-ray binaries is also discussed.
“…This finding shows promise for the use of PLLA and CSNF layered films as new packaging materials. CSNF originate from natural cellulose and are degradable [8,9]. Natural cellulose is the most abundant biomass, and consists of slender microfibrils with diameters ranging from 2 to 20 nm depending on their biological origin [10].…”
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