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Reactivity of Silicon tetrachloride and Trimethylsilyl chloride with O, O’-Bis (α-Naphthyl, β-Naphthyl or 2, 3, 5-trimethylphenyl) dithiophosphate ligands

“…These ligands show bidentate [4][5][6][7][8][9][10], monodentate [11,13] and also bridging mode of bonding with metals and metalloids [14]. Various dithiophosphato derivatives finds extensive applications in agriculture [15], industries such as extreme pressure oil additives [16], heat stabilizers for polymers [17], hydraulic fluid additives [18], extraction [19], analytical [20] and also show biologiocal activities [21] Literature survey revealed that substantial amount of work has been done with the dialkyl and alkylene ligands with silicon and no information are available on the derivatives of O,O'-Bis(α-Naphthyl, β-Naphthyl or 2,3,5-trimethylphenyl) dithiophosphate ligands, [22][23][24][25].…”

Convenient Route to Alkylene Dithiophosphato Ligands: Synthesis and Crystallographic Analysis of [OCH2CMe2CH2OPS2HNEt3]

“…Subsequently, cyclic analogous alkylene dithiophosphoric acids, OGOPS 2 H, (where G = 1,2-and 1,3-glycols) were reported by Bhasin et al [15]. Later, several papers have been published on metal/metalloid derivatives of alkylene dithiophosphates [16][17][18][19][20][21][22][23][24] depicting the versatile nature of these ligands. In general, universal bi-dentate nature of these ligands have been established [25][26][27][28] with few exceptions in compounds with triorganotin(IV) moieties, where these behaved in less common monodentate linkages [29,30].…”

New Organic Derivatives of O,O′-(o-, m-, and p-Ditolyl)/Dibenzyldithiophosphates: Synthesis and Characterization

“…[11][12] A variety of complexes have been reported with these ligands, in which they have predominantly exhibited a bidentate mode of bonding. [13][14][15][16][17][18][19] However, the less common monodentate linkage has also been depicted by these ligands, such as in the case of nickel and tin. [20][21] A literature survey revealed scant information on the derivatives of O,O -ditolyldithiophosphate ligands compared to dialkyl-and alkylenedithiophosphates.…”