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Sidyakin, M. V.; Cholodovitch, A. N.; Ivanov, Evgeniy; Решетников, С. И.; Startsev, A. N.

doi:10.1023/a:1020831801420

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“…The benzene hydrogenation was studied in an isothermal reactor with the fixed catalyst bed [4]. Dihydrogen was passed through a saturator filled either with pure benzene or with a mixture of benzene and thiophene in the molar ratio 9 : 1.…”

Section: Methodsmentioning

confidence: 99%

Kinetic behavior of benzene hydrogenation and thiophene hydrogenolysis on sulfide Ni-Mo/Al2O3 catalyst

Ivanov

Решетников

Sidyakin

et al. 2006

React Kinet Catal Lett

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An unsteady-state kinetic model of both benzene hydrogenation (HDA) and thiophene hydrogenolysis (HDS) on a sulfide hydrotreating catalyst Ni-Mo/Al 2 O 3 has been developed. The model adequately describes experimental data obtained at the pressure 2 MPa, temperature 573 K and at various contact times and ratios of benzene/thiophene. The model is based on the assumption that the catalyst surface contains only one type of active sites, i.e., Ni atoms in the sulfide bimetallic species, which are responsible for both hydrogenolysis and hydrogenation reactions.

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Section: Methodsmentioning

confidence: 99%