“…[6,14] Halogen (Cl, Br, I) in glass systems is monovalent, which forms non-bridging structural motif with the free electrons. [16,17] High atomic-mass halogens bonding with Sb increases the complexity and randomness of the network connectivity, thus inhibiting the crystal formation of Sb 2 S 3 . Consequently, stable bulk glasses of Sb-S-I system can be fabricated, whose microstructure is built by a weak interaction among [SbS 3 ], [SbS 3−x I x ], and [SbI 3 ] pyramids.…”