Abstract:The title compound, C 19 H 14 O 4 , crystallizes with two molecules in the asymmetric unit. The dihydropyran rings adopt a halfchair conformation or a conformation intermediate between a sofa and half-chair. The inversion-related type A and B molecules and vice versa are linked by CÐHÁ Á ÁO hydrogen bonds, forming an in®nite chain along the a axis. The molecular packing is stabilized by CÐHÁ Á ÁO interactions. Comment Coumarin derivatives can undergo photocycloaddition with themselves (Song et al., 1971). Coum… Show more
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