5-HMF production from glucose using ion exchange resin and alumina as a dual catalyst in a biphasic system

Pumrod, Supakrit; Kaewchada, Amaraporn; Roddecha, Supacharee; Jaree, Attasak

doi:10.1039/c9ra09997b

Cited by 29 publications

(15 citation statements)

References 36 publications

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“…5-HMF is produced by triple dehydration of fructose, which is derived from glucose isomerization. Direct production of 5-HMF from cellulose involves subsequent steps of acid-catalyzed hydrolysis of cellulose, Lewis acid- or base-catalyzed isomerization of glucose to fructose, and finally acid-catalyzed fructose dehydration . 5-HMF further hydrolyses with water to form levulinic acid; thus direct synthesis is difficult under hydrothermal conditions which is a prerequisite for cellulose hydrolysis.…”

Section: Catalytic Processes For Production Of Furfural Levulinic Aci...mentioning

confidence: 99%

“…Direct production of 5-HMF from cellulose involves subsequent steps of acid-catalyzed hydrolysis of cellulose, Lewis acid-or base-catalyzed isomerization of glucose to fructose, and finally acid-catalyzed fructose dehydration. 106 5-HMF further hydrolyses with water to form levulinic acid; thus direct synthesis is difficult under hydrothermal conditions which is a prerequisite for cellulose hydrolysis. Table 4 shows glucose and fructose dehydration to 5-HMF using various metal oxides/supported metal oxides.…”

Section: Catalytic Processes For Production Of Furfural Levulinic Aci...mentioning

confidence: 99%

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Advances in Upgrading Biomass to Biofuels and Oxygenated Fuel Additives Using Metal Oxide Catalysts

Ethiraj¹,

Wagh

Manyar

2022

Energy Fuels

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Increasing demand for transportation fuels, awareness of climate change, and dwindling supplies of crude oil has led to the rapid increase in production of biomass derived oxygenated fuel additives as viable drop-in fuels for potential blending with conventional fuels. The biorefinery processes for synthesis of oxygenated fuel additives using metal oxide catalysts in various forms have evolved significantly. Metal oxides exhibit diverse structures and physiochemical properties including acidity, basicity, and redox nature along with the lattice oxygen vacancies, which by careful design and modification can be tuned to optimize high catalytic activity and selectivity in several organic transformations. Metal oxide based catalysts can be designed for use in industries, as individual metal oxides or mixed metal oxides, decorated with noble and non-noble metal nanoparticles, porous metal oxides, and sulfonated metal oxides. In this review, we have attempted to consolidate the progress made with catalytic applications of metal oxides in the synthesis and production of oxygenated fuel additives through several important biorefinery processes.

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Section: Catalytic Processes For Production Of Furfural Levulinic Aci...mentioning

confidence: 99%

Section: Catalytic Processes For Production Of Furfural Levulinic Aci...mentioning

confidence: 99%

Advances in Upgrading Biomass to Biofuels and Oxygenated Fuel Additives Using Metal Oxide Catalysts

Ethiraj¹,

Wagh

Manyar

2022

Energy Fuels

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“…Two pathways are proposed: In the first one, glucose is initially converted to fructose by isomerization over a Lewis-acid catalyst followed by dehydration to HMF over a Brønsted-acid catalyst (Figure ). − Recently, Nakajima et al proposed stepwise dehydration of HMF directly from glucose via the formation of unstable carbonyl intermediates. This stepwise dehydration is mainly realized on NbOx and TiOx types of materials. , …”

Section: Amination Of Biomass-derived Oxygenatesmentioning

confidence: 99%

Toward Renewable Amines: Recent Advances in the Catalytic Amination of Biomass-Derived Oxygenates

et al. 2022

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Synthesis of high-value-added chemicals from biomass and/or biomass-derived platform molecules is considered an important strategy to mitigate the global dependency on fossil resources and include renewable resources in a circular economy. In recent years, the synthesis of bio-based plastics has received significant attention as a potential alternative to conventional industrial processes. Thus, a lot of effort has been put into the development of not only different classes of biomonomers but also bio-based drop-in chemicals. Amine-derived molecules, especially alcohol-amines, diamines, and N-heterocyclic amines, are the most important classes of functional monomers for the production of polyamides, polyimides, polyurethanes, and polyureas. Additionally, these amines are extensively used in pharmaceuticals. In this review, we will give a concise overview of the up-to-date methods for the production of industrially important amines from biomass-derived oxygenates. Special attention will be given to the catalytic amination of biomass aldehyde- and alcohol-based oxygenates, reaction mechanism, catalyst stability, as well as their specific challenges and opportunities. We anticipate this critical and comprehensive review to provide detailed insights into the synthesis of bio-based amines and guide the development of effective greener synthetic methodologies.

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“…They have great potential for transformation of biomass efficiently. Recently, various types of solid acid catalysts, including zeolites, cation-exchange resins, carbonaceous solid acids, transition-metal oxides, catalyst-supported solid acids, and heteropoly compounds, have been applied in glucose conversion. The mechanisms of HMF formation from glucose, as well as recent achievements in one-pot glucose conversion into HMF, are reviewed in this section.…”

Section: Thermal Catalytic Transformations Of Biomass-derived Glucosementioning

confidence: 99%

Thermal Catalytic Conversion of Biomass-Derived Glucose to Fine Chemicals

Wang

Huang

et al. 2021

Energy Fuels

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The energy crisis is a major challenge for the 21st century due to fossil fuel depletion. Biomass, the waste material from plants or animals containing renewable and abundant carbon resources, is considered as an ideal alternative for fossil fuels. Glucose, as a building unit of cellulose, is the most widely used monosaccharide that has wide applications ranging from pharmaceuticals and food industries. The conversion of biomassderived glucose has become a major and multidisciplinary field of research. Various catalytic transformation processes have been used in the thermochemical conversion of glucose. Numerous nanocatalysts have been developed to selectively convert biomassderived glucose into fine chemicals. This review mainly summarizes the recent achievements of developing catalytic systems for glucose conversion into high-value chemicals. The catalyst structure−activity relationships and underlying reaction mechanisms are also discussed.

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5-HMF production from glucose using ion exchange resin and alumina as a dual catalyst in a biphasic system

Cited by 29 publications

References 36 publications

Advances in Upgrading Biomass to Biofuels and Oxygenated Fuel Additives Using Metal Oxide Catalysts

Advances in Upgrading Biomass to Biofuels and Oxygenated Fuel Additives Using Metal Oxide Catalysts

Toward Renewable Amines: Recent Advances in the Catalytic Amination of Biomass-Derived Oxygenates

Thermal Catalytic Conversion of Biomass-Derived Glucose to Fine Chemicals

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