5‐Carboxymethyl‐2‐(4‐methylthiophenyl)‐1,3,2‐dioxaborolan‐4‐one: synthesis, characterization and application in enantioselective reduction of ketones

5-Carboxymethyl-2-(4-methylthiophenyl)-1,3,2-dioxaborolan-4-one: Synthesis, Characterization and Application in EnantioselectiveReduction of Ketones. -A general way to synthesize (acyloxy)boronates from malic acid is described. The optically active title compound shows remarkable reactivity in the enantioselective reduction of acetophenones. -(GORSKA, A.; HAJMOWICZ, H.; KLIS*, T.; SERWATOWSKI, J.; SYNORADZKI, L.; Appl. Organomet. Chem. 25 (2011) 4, 294-297, http://dx.doi.org/10.1002/aoc.1757 ; Phys. Chem. Dep., Fac. Chem., Warsaw Univ. Technol., PL-00-664 Warszawa, Pol.; Eng.) -Bartels 33-055

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ChemInform Abstract: 5‐Carboxymethyl‐2‐(4‐methylthiophenyl)‐1,3,2‐dioxaborolan‐4‐one: Synthesis, Characterization and Application in Enantioselective Reduction of Ketones.

Górska

Hajmowicz

Kliś

et al. 2011

ChemInform

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5‐Carboxymethyl‐2‐(4‐methylthiophenyl)‐1,3,2‐dioxaborolan‐4‐one: synthesis, characterization and application in enantioselective reduction of ketones

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ChemInform Abstract: 5‐Carboxymethyl‐2‐(4‐methylthiophenyl)‐1,3,2‐dioxaborolan‐4‐one: Synthesis, Characterization and Application in Enantioselective Reduction of Ketones.

ChemInform Abstract: 5‐Carboxymethyl‐2‐(4‐methylthiophenyl)‐1,3,2‐dioxaborolan‐4‐one: Synthesis, Characterization and Application in Enantioselective Reduction of Ketones.

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