440. Some sulphides containing the 2-chloroethyl group

Goldsworthy, L. J.; Harding, G. F.; Norris, W. L.; Plant, S. G. P.; Selton, B.

doi:10.1039/jr9480002177

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Sulfur Alkylation2

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1950

1995

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Cited by 7 publications

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“…Cook and Moss (85) have patented a process for the reaction of appropriate tertiary amines with alkyl halides, dialkyl sulfates, etc., to produce quaternary ammonium compounds of the type acid radical with ClCH2CH2OPh or a halobenzyl derivative. Rieveschl (190) reacted an alkyl halide with derivatives of Ph2CHOCH2CH2NH2 to form quaternary ammonium halides.…”

Section: Nitrogen Alkylationmentioning

confidence: 99%

“…These compounds are useful as solvents, plasticizers, corrosion inhibitors, etc. A description of the preparation of some thio ethers by means of an alcohólate catalyst is given by Goldsworthy and co-workers (85). A French patent (115) discusses the sulfur alkylation of thioammeline by means of agents such as dimethyl sulfate in alkaline medium.…”

Section: Sulfur Alkylationmentioning

confidence: 99%

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Alkylation

Shreve¹

1950

Ind. Eng. Chem.

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Section: Nitrogen Alkylationmentioning

confidence: 99%

Section: Sulfur Alkylationmentioning

confidence: 99%

Alkylation

Shreve¹

1950

Ind. Eng. Chem.

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2,4,8,10‐Tetraoxa‐3,9‐diphosphaspiro[5.5]undecane‐3,9‐disulfide and Some Derived Compounds

Rätz

Bliss

1966

Journal of Heterocyclic Chem

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2,4,8,10‐Tetraoxa‐3,9‐diphosphaspiro[5.5]undecane‐3,9‐disulfide (I) has been prepared by the treatment of 3, 9‐dichloro‐2,4,8,10‐tetraoxa‐3,9‐diphosphaspiro[5.5]undecane (II) with hydrogen sulfide. The reactions of I with thiocyanates to give esters of 3,9‐dimercapto‐2,4,8,10‐tetraoxa‐3,9‐diphosphaspiro[5.5]undecane‐3, 9‐disulfide (III) and with isocyanates and isothiocyanates to give P‐carbamoyl and thiocarbamoyl derivatives of I were investigated. I was also found to condense with chloral to produce an α‐hydroxy‐thiophosphonate (XXVIII), but similar reactions with other aldehydes failed to yield analogous products.

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