4-(Nitroalkyl- and dinitroalkyl-ONN-azoxy)-3-cyanofuroxans and some of their derivatives

Parakhin, V. V.; Shlykova, N. I.; ́yanov, O. A. Luk

doi:10.1007/s11172-017-1734-7

Cited by 5 publications

(1 citation statement)

References 27 publications

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“…Based on the oxidative couplings between primary amines and nitroso compounds, a series of azoxy energetic compounds were synthetized by Parakhin et al using 4-amino-3-cyanofuroxan 2 as starting materials ( Parakhin et al, 2017 ). The azoxy intermediate 22 obtained by reacting with 1,1-dinitro-1-nitroethane further reacted with TMSN 3 by [3 + 2] cycloaddition, and tetrazolyl was successfully introduced to obtain a new energetic compound 23 .…”

Section: Synthesis Of Nitrogen-rich Energetic Compoundsmentioning

confidence: 99%

Synthetic Strategies Toward Nitrogen-Rich Energetic Compounds Via the Reaction Characteristics of Cyanofurazan/Furoxan

Wang¹,

Zhai²,

She³

et al. 2022

Front. Chem.

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The structural units of amino-/cyano-substituted furazans and furoxans played significant roles in the synthesis of nitrogen-rich energetic compounds. This account focused on the synthetic strategies toward nitrogen-rich energetic compounds through the transformations based on cyanofurazan/furoxan structures, including 3-amino-4-cyanofurazan, 4-amino-3-cyano furoxan, 3,4-dicyanofurazan, and 3,4-dicyanofuroxan. The synthetic strategies toward seven kinds of nitrogen-rich energetic compounds, such as azo (azoxy)-bridged, ether-bridged, methylene-bridged, hybrid furazan/furoxan-tetrazole–based, tandem furoxan–based, hybrid furazan-isofurazan–based, hybrid furoxan-isoxazole–based and fused framework–based energetic compounds were fully reviewed, with the corresponding reaction mechanisms toward the nitrogen-rich aromatic frameworks and examples of using the frameworks to create high energetic substances highlighted and discussed. The energetic properties of typical nitrogen-rich energetic compounds had also been compared and summarized.

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Section: Synthesis Of Nitrogen-rich Energetic Compoundsmentioning

confidence: 99%

Synthetic Strategies Toward Nitrogen-Rich Energetic Compounds Via the Reaction Characteristics of Cyanofurazan/Furoxan

Wang¹,

Zhai²,

She³

et al. 2022

Front. Chem.

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Synthesis and Characterization of 3‐(5‐(Fluorodinitromethyl)‐1H‐1,2,4‐triazol‐3‐yl)‐4‐nitrofurazan: A Novel Promising Energetic Component of Boron‐based Fuels for Rocket Ramjet Engines

Sheremetev

Aleksandrova

Semyakin

et al. 2019

Chemistry An Asian Journal

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The synthesis of a new energetic 1,2,4‐triazole compound bearing nitrofurazanyl and fluorodinitromethyl units, which may find use as a component for rocket ramjet engines (RRE), is described. The target product was prepared in a four‐step process applying oxidation/nitration/decarboxylation/fluorination reactions and is fully characterized. Its density and structural features were uniquely determined by X‐ray analysis. It is shown that replacing HMX with the compound of this study in boron‐based fuels gives an increase in energy.

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3-(1-Methyl-1-nitroethyl-1-ONN-azoxy)-4-aminofuroxan. Synthesis and transformations of the amino group

2018

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4-(Nitroalkyl- and dinitroalkyl-ONN-azoxy)-3-cyanofuroxans and some of their derivatives

Cited by 5 publications

References 27 publications

Synthetic Strategies Toward Nitrogen-Rich Energetic Compounds Via the Reaction Characteristics of Cyanofurazan/Furoxan

Synthetic Strategies Toward Nitrogen-Rich Energetic Compounds Via the Reaction Characteristics of Cyanofurazan/Furoxan

Synthesis and Characterization of 3‐(5‐(Fluorodinitromethyl)‐1H‐1,2,4‐triazol‐3‐yl)‐4‐nitrofurazan: A Novel Promising Energetic Component of Boron‐based Fuels for Rocket Ramjet Engines

3-(1-Methyl-1-nitroethyl-1-ONN-azoxy)-4-aminofuroxan. Synthesis and transformations of the amino group

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