The molecule of the title compound, C26H18F2O8S2, lies across a crystallographic twofold rotation axis. The benzene rings of the 4-fluorobenzoyl groups make dihedral angles of 78.93 (12)° with the naphthalene ring system. An intramolecular C—H⋯π interaction occurs. In the crystal, a number of C—H⋯O interactions link the molecules, forming a three-dimensional structure.