[4-(Diethylamino)benzoato-κO]triphenyltin(IV)

Abstract

Key indicatorsSingle-crystal X-ray study T = 100 K Mean (C-C) = 0.002 Å R factor = 0.027 wR factor = 0.072 Data-to-parameter ratio = 43.8For details of how these key indicators were automatically derived from the article, see

Synthesis, crystal structures and spectroscopic properties of two new organotin (IV) complexes and their antiproliferative effect against cancerous and non-cancerous cells

“…However, from the molecular structure diagram, the tin atom of complex 2 was bonded to an oxygen atom (Sn-O) of the carboxylate group while the other three bonds were attributed to the bonding between the carbons of the phenyl group to the tin atom (Sn-C), resulting in the tin atom being tetra-coordinated. The bond lengths and angles of complex 2 have normal values and agree with those found for related structures [30,52].…”

“…3, the tin atom was found to be tetra-coordinated as generally found for triphenyltin(IV) carboxylate complexes [30,52]. It is believed that the geometry occupied by the tin atom of the title complex is a distorted tetrahedral [30,52]. However, from the molecular structure diagram, the tin atom of complex 2 was bonded to an oxygen atom (Sn-O) of the carboxylate group while the other three bonds were attributed to the bonding between the carbons of the phenyl group to the tin atom (Sn-C), resulting in the tin atom being tetra-coordinated.…”

“…Based on the crystal structure, depicted in Fig. 3, the tin atom was found to be tetra-coordinated as generally found for triphenyltin(IV) carboxylate complexes [30,52]. It is believed that the geometry occupied by the tin atom of the title complex is a distorted tetrahedral [30,52].…”

“…The organotin(IV) complexes show interesting coordination geometries as well as structural diversity, which could expand from simple, monomeric to polymeric structures [8,[29][30][31][32][33][34][35]. This gives biological significance to the tin complexes where their coordination motives and geometry can be monitored.…”

Preliminary in vitro Cytotoxic Assay on HepG2 and Antibacterial Screening Activity: Synthesis and Characterization of Organotin(IV) Complexes Derivatives of 2-Methyl-3-nitrobenzoic Acid

“…In general, the coordination chemistry of organotin(IV) complexes are extensively studied due to its coordination geometries as well as structural diversity (monomer, dimeric, hexameric and oligomeric) [1][2][3][4][5] . It was also well-documented that the participation of coordinating solvent molecules to tin(IV) atoms moieties and its coordination sphere will influence the overall structural of organotin(IV) complexes 3,4,6 .…”