4-Chloro-N-(4-chlorophenylsulfonyl)-N-(3-oxo-2,3-dihydro-1,2-benzisothiazol-2-yl)benzenesulfonamide

Abstract

In the title compound, C19H12Cl2N2O5S3, the benzene rings of the chloro­phenyl­sulfonyl groups form a dihedral angle of 35.85 (8)° and are inclined at angles of 23.51 (6) and 59.22 (6)° with respect to the essentially planar benzisothia­zole ring system [maximum deviation = 0.030 (2) Å]. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯O hydrogen bond. In the crystal packing, mol­ecules are linked into chains parallel to the a axis by inter­molecular C—H⋯O hydrogen bonds and π–π stacking inter­actions, with centroid–centroid distances of 3.592 (5) Å.

Crystal structure and Hirshfeld surface analysis of N-[2-(5-methylfuran-2-yl)phenyl]-3-nitro-N-[(3-nitrophenyl)sulfonyl]benzenesulfonamide

“…The nine related compounds found as a result of the search for 'N-(methanesulfonyl)-N-methyl methanesulfonamide' in the Cambridge Structural Database (CSD, Version 5.42, update of September 2021; Groom et al, 2016) are for N-(2-formylphenyl)-4-methyl-N-[(4-methylphenyl)sulfonyl]benzenesulfonamide, i.e. CSD refcodes JOBTIF (Kim, 2014), CEGMIM (Mughal et al, 2012a), YAXKAL (Taher & Smith, 2012a), OCABUR (Abbassi et al, 2011), CEGSUE (Mughal et al, 2012b), EFASUB (Taher & Smith, 2012b), PONZIC (Rizzoli et al, 2009), AYUPUG (Arshad et al, 2011) and ROGJON (Li & Song, 2008).…”

Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide

“…Ten related compounds were found as a result of the search for 'N-(methanesulfonyl)-N-methylmethanesulfonamide' in the Cambridge Structural Database (CSD, Version 5.42, update of September 2021; Groom et al, 2016), viz. PIMGUR (Mammadova et al, 2023), JOBTIF (Kim, 2014), CEGMIM (Mughal et al, 2012a), CEGSUE (Mughal et al, 2012b), YAXKAL (Taher & Smith, 2012a), EFASUB (Taher & Smith, 2012b), OCABUR (Abbassi et al, 2011), AYUPUG (Arshad et al, 2011), PONZIC (Rizzoli et al, 2009) and ROGJON (Li & Song, 2008).…”