Abstract:The title compound features a doubly protonated dimethyl‐ and bis(methylcarboxamide)‐substituted tetraazacyclotetradecane with the pendant arms disposed over the cavity, an arrangement that is facilitated by intramolecular hydrogen‐bonding interactions. The dication occupies a special position about an inversion centre, whereas the ClO4− anion and the water molecule are in general positions, thus forming a crystal with the overall composition C16H36N6O22+·2ClO4−·2H2O. The crystal structure is stabiliz… Show more
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