3d Transition metal doping induced charge rearrangement and transfer to enhance overall water-splitting on Ni<sub>3</sub>S<sub>2</sub>(101) facet: a first-principles calculation study

Zhang, Minghao; Shao, Xiaodong; Liu, Lu; Xu, Xiaoyong; Pan, Jing; Hu, Jingguo

doi:10.1039/d2ra04252e

Cited by 8 publications

(2 citation statements)

References 44 publications

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“…Ir and Ru are also precious metals showing outstanding HER activities [277,278]. Due to the reasons mentioned above, for the past few years, catalysts based on transition metals, such as Fe, Zr, Co, Nb, Ni, and V, have been explored as alternatives [277][278][279][280][281][282][283].…”

Section: Porous Non-precious Metals Mofs and Their Nanostructuresmentioning

confidence: 99%

“…Ni-based catalysts, for example, are attractive since they exhibit alkaline stability and alkaline electroactivity [277][278][279][280][281][282][283]. One modification of Ni to improve its electrocatalytic activity is via the formation of nanoparticles/nanostructures (including porous ones) on the surface, which achieves this by enhancing the conductivity [284,285].…”

Section: Porous Non-precious Metals Mofs and Their Nanostructuresmentioning

confidence: 99%

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Porous Inorganic Nanomaterials: Their Evolution towards Hierarchical Porous Nanostructures

Jose,

Mathew,

Fernández-Navas

et al. 2024

Micro

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The advancement of both porous materials and nanomaterials has brought about porous nanomaterials. These new materials present advantages both due to their porosity and nano-size: small size apt for micro/nano device integration or in vivo transport, large surface area for guest/target molecule adsorption and interaction, porous channels providing accessibility to active/surface sites, and exposed reactive surface/active sites induced by uncoordinated bonds. These properties prove useful for the development of different porous composition types (metal oxides, silica, zeolites, amorphous oxides, nanoarrays, precious metals, non-precious metals, MOFs, carbon nanostructures, MXenes, and others) through different synthetic procedures—templating, colloidal synthesis, hydrothermal approach, sol-gel route, self-assembly, dealloying, galvanostatic replacement, and so—for different applications, such as catalysis (water-splitting, etc.), biosensing, energy storage (batteries, supercapacitors), actuators, SERS, and bio applications. Here, these are presented according to different material types showing the evolution of the structure design and development towards the formation of hierarchical porous structures, emphasizing that the formation of porous nanostructures came about out of the desire and need to form hierarchical porous nanostructures. Common trends observed across these different composition types include similar (aforementioned) applications and the use of porous nanomaterials as templates/precursors to create novel ones. Towards the end, a discussion on the link between technological advancements and the development of porous nanomaterials paves the way to present future perspectives on these nanomaterials and their hierarchical porous architectures. Together with a summary, these are given in the conclusion.

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Section: Porous Non-precious Metals Mofs and Their Nanostructuresmentioning

confidence: 99%

Section: Porous Non-precious Metals Mofs and Their Nanostructuresmentioning

confidence: 99%

Porous Inorganic Nanomaterials: Their Evolution towards Hierarchical Porous Nanostructures

Jose,

Mathew,

Fernández-Navas

et al. 2024

Micro

View full text Add to dashboard Cite

show abstract

Recent advances in Ni (oxy) hydroxides and Ni sulfides catalysts for oxygen evolution reactions

Ou,

Ye,

Zhou

2023

Coordination Chemistry Reviews

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Construction active sites in nickel sulfide by dual-doping vanadium/cobalt for highly effective oxygen evolution reaction

Zhang,

Liu,

Zhou

et al. 2024

Journal of Colloid and Interface Science

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3d Transition metal doping induced charge rearrangement and transfer to enhance overall water-splitting on Ni₃S₂(101) facet: a first-principles calculation study

Abstract: Cost-efficient bifunctional electrocatalysts with good stability and high activity are in great demand to replace noble-metal-based catalysts for overall water-splitting.

Cited by 8 publications

References 44 publications

Porous Inorganic Nanomaterials: Their Evolution towards Hierarchical Porous Nanostructures

Porous Inorganic Nanomaterials: Their Evolution towards Hierarchical Porous Nanostructures

Recent advances in Ni (oxy) hydroxides and Ni sulfides catalysts for oxygen evolution reactions

Construction active sites in nickel sulfide by dual-doping vanadium/cobalt for highly effective oxygen evolution reaction

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3d Transition metal doping induced charge rearrangement and transfer to enhance overall water-splitting on Ni3S2(101) facet: a first-principles calculation study

Abstract: Cost-efficient bifunctional electrocatalysts with good stability and high activity are in great demand to replace noble-metal-based catalysts for overall water-splitting.

Cited by 8 publications

References 44 publications

Porous Inorganic Nanomaterials: Their Evolution towards Hierarchical Porous Nanostructures

Porous Inorganic Nanomaterials: Their Evolution towards Hierarchical Porous Nanostructures

Recent advances in Ni (oxy) hydroxides and Ni sulfides catalysts for oxygen evolution reactions

Construction active sites in nickel sulfide by dual-doping vanadium/cobalt for highly effective oxygen evolution reaction

Contact Info

Product

Resources

About

3d Transition metal doping induced charge rearrangement and transfer to enhance overall water-splitting on Ni₃S₂(101) facet: a first-principles calculation study