2019
DOI: 10.1021/acs.langmuir.9b03116
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3D Organic Nanofabrics: Plasma-Assisted Synthesis and Antifreezing Behavior of Superhydrophobic and Lubricant-Infused Slippery Surfaces

Abstract: Herein, we present the development of supported organic nanofabrics formed by a conformal polymer-like interconnection of small-molecule organic nanowires and nanotrees. These organic nanostructures are fabricated by a combination of vacuum and plasma-assisted deposition techniques to generate step by step, single-crystalline organic nanowires forming one-dimensional building blocks, organic nanotrees applied as three-dimensional templates, and the polymer-like shell that produces the final fabric. The complet… Show more

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Cited by 12 publications
(11 citation statements)
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“…The application of adamantane thin films to produce slippery liquid-infused porous surfaces (SLIPS) with the 3D structure has also been reported [139]. These polymer-like adamantane films were deposited on the 3D organic nanofabric by the RPAVD technique to produce an amorphous and continuous layer.…”
Section: Diamondoid Thin Filmsmentioning
confidence: 99%
“…The application of adamantane thin films to produce slippery liquid-infused porous surfaces (SLIPS) with the 3D structure has also been reported [139]. These polymer-like adamantane films were deposited on the 3D organic nanofabric by the RPAVD technique to produce an amorphous and continuous layer.…”
Section: Diamondoid Thin Filmsmentioning
confidence: 99%
“…In this section, we will show the extension of the results above to a soft-template method for the fabrication of core@shell nanowires and nanotubes. Such a method has been developed during the last years for the synthesis of supported and on-device nanowires and nanotubes with applications as superhydrophobic and antifreezing surfaces, nanoscale waveguides, nanosensors, excitonic solar cell photoelectrodes, and piezoelectric nanogenerators (Borras et al, 2009;Macias-Montero et al, 2013Filippin et al, 2017bFilippin et al, , 2019Alcaire et al, 2019b). Scheme 2 presents the main steps for the fabrication of these hierarchical nanostructures.…”
Section: Development Of Hybrid Metal and Metal Oxide Core@shell Nanmentioning
confidence: 99%
“…Metal and metal oxide thin films and nanoparticles deposited on a substrate as well as polymeric and organic surfaces have been demonstrated as suitable nucleation centers for the formation of small-molecule organic nanowires. In our previous articles (Borras et al, 2008(Borras et al, , 2009(Borras et al, , 2010Macias-Montero et al, 2013Filippin et al, 2017bFilippin et al, , 2019Alcaire et al, 2019b) we have optimized the process for Au, Ag, ITO, ZnO, TiO 2 , SiO 2 , PDMS, and organic substrates (Step i) and molecules as metal -porphyrins, -phthalocyanines and perylenes working as the nanowires building blocks (Step ii). Scheme 2 right shows SEM images of the different steps during the formation of the core@shell nanowires.…”
Section: Development Of Hybrid Metal and Metal Oxide Core@shell Nanmentioning
confidence: 99%
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“…However, lubricant depletion is a common problem for SLIPSs, which can be due to gravitational drainage [38,39], evaporation [40][41][42], high-speed drop impact [43,44], growth of frost or ice [44][45][46], formation of wetting ridges and cloaking layers [47], and shear flow impact [48,49]. Although some of the causes of lubricant depletion can be circumvented, such as gravitational drainage (by using appropriate substrates with micro/nanostructures) [50,51] and evaporation (by replacing lubricants with nonvolatile oils, such as ionic liquids) [41], lubricant depletion is difficult to avoid. Therefore, a surface with a continuous oil supply can effectively overcome this situation.…”
Section: Introductionmentioning
confidence: 99%