3D Ordered Macroporous Carbon Encapsulated ZnO Nanoparticles as a High‐Performance Anode for Lithium‐Ion Batteries

Zhang, Chengwei; Zhang, Zheng; Yin, Fuxing; Zhang, Yongguang; Mentbayeva, Almаgul; Babaa, Moulay-Rachid; Molkenova, Anara; Bakenov, Zhumabay

doi:10.1002/celc.201700239

Cited by 19 publications

(2 citation statements)

References 41 publications

(55 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…165 Zhang et al prepared a 3D ordered macroporous carbon (3DOMC), which, when prepared with silica crystals as a template, has ordered macropores and mesopore walls. 166 Park et al reported 3D porous microspheres using hollow NiCo 2 O 4 polyhedron (H-NCO/CNT)-modified interconnected carbon nanotubes (CNT) as materials for LIBs. Using a combination of spray pyrolysis and solution methods, a composite with reasonable design was successfully prepared.…”

Section: Mo Nanocompositesmentioning

confidence: 99%

A Comprehensive Review on Metal-Oxide Nanocomposites for High-Performance Lithium-Ion Battery Anodes

Chen

Zhang

2021

Energy Fuels

View full text Add to dashboard Cite

In recent years, lithium-ion batteries (LIBs) have been widely used in the fields of small electronic devices, wearable electronic devices, and electric vehicles, because of their high energy density and good rate performance. Commercial LIBs generally use carbonaceous materials as anodes. Although carbonaceous materials have the advantages of low price and simple manufacture, carbonaceous anodes such as graphite have a fatal flaw, that is, their theoretical capacity is only 372 mA h g −1 , which will greatly limit the development of large-capacity LIBs. The development of highperformance anode materials is essential for the further application of LIBs. Many works show that by further adopting reasonable structural design to manufacture nanocomposites, better performance can be obtained. In this review, we introduce and discuss the development of metal oxide (MO) and MO nanocomposites for LIB anodes. Some advanced nanostructures of MO nanocomposites, such as core−shell structure, low-dimensional structure, and porous structure, are summarized. This review comprehensively analyzes the application of MO nanocomposites for LIB anodes in recent years.

show abstract

Section: Mo Nanocompositesmentioning

confidence: 99%

A Comprehensive Review on Metal-Oxide Nanocomposites for High-Performance Lithium-Ion Battery Anodes

Chen

Zhang

2021

Energy Fuels

View full text Add to dashboard Cite

show abstract

“…Utilizing ZnO has several advantages, such as simple synthesis methods, abundant reserves on the Earth, and the fact that it is environmentally friendly [13]. Most importantly, the theoretical specific capacity of ZnO is 978 mAh g −1 , which leads this to be a good potential material for LIBs [14].…”

Section: Introductionmentioning

confidence: 99%

Synthesis of the ZnO@ZnS Nanorod for Lithium-Ion Batteries

Wang

Zhao

et al. 2018

Energies

View full text Add to dashboard Cite

Abstract:The ZnO@ZnS nanorod is synthesized by solvothermal method as an anode material for lithium ion batteries. ZnS is deposited on ZnO and assembles in nanorod geometry successfully. The nanosized rod structure supports ion diffusion by substantially reducing the ion channel. The close-linking of ZnS and ZnO improves the synergetic effect. ZnS is in the middle of the ZnO core and the external environment, which would greatly relieve the volume change of the ZnO core during the Li + intercalation/de-intercalation processes; therefore, the ZnO@ZnS nanorod is helpful in maintaining excellent cycle stability. The ZnO@ZnS nanorod shows a high discharge capacity of 513.4 mAh g −1 at a current density of 200 mA g −1 after 100 cycles, while a reversible capacity of 385.6 mAh g −1 is achieved at 1000 mA g −1 .

show abstract

Nanospace‐Confinement Synthesis: Designing High‐Energy Anode Materials toward Ultrastable Lithium‐Ion Batteries

Jiang

Zhang

Chen

et al. 2020

Small

View full text Add to dashboard Cite

Exploiting high‐capacity and durable electrode materials is pivotal to developing lithium‐ion batteries (LIBs) and their applications. Multiscaled nanomaterials have been demonstrated to efficiently couple the advantages of each component on different scales in energy storage fields. However, the precise control of the microstructure remains a great challenge for maximizing their contributions. Nanospace‐confined synthesis provides a proactive strategy to build novel multiscaled nanomaterials with controllable internal void space for circumventing the intrinsic volume effects in the charge/discharge process. Herein, the rational design and synthesis of multiscaled high‐capacity anode materials are mainly summarized according to their electrochemical mechanisms by choosing 1D channel, 2D interlayer, and 3D space as representative confinement reaction environments. The structure–performance relationships are clarified with the assistance of quantitative calculations, molecular simulations, and so forth. Finally, future potentials and challenges of such a synthesis tactic in designing high‐performance electrode materials for next‐generation secondary batteries are outlooked.

show abstract

3D Ordered Macroporous Carbon Encapsulated ZnO Nanoparticles as a High‐Performance Anode for Lithium‐Ion Batteries

Cited by 19 publications

References 41 publications

A Comprehensive Review on Metal-Oxide Nanocomposites for High-Performance Lithium-Ion Battery Anodes

A Comprehensive Review on Metal-Oxide Nanocomposites for High-Performance Lithium-Ion Battery Anodes

Synthesis of the ZnO@ZnS Nanorod for Lithium-Ion Batteries

Nanospace‐Confinement Synthesis: Designing High‐Energy Anode Materials toward Ultrastable Lithium‐Ion Batteries

Contact Info

Product

Resources

About