The coefficient of friction, m, of PBX 9404 was measured on stainless steel, aluminum, polytetrafluoroethylene (PTFE), and the explosive itself between ambient and 135 C at a rotational speed of 0.0025 rad=s. The mean surface roughness, R a , of the various materials was analyzed by an optical profilometer. For PBX 9404 on stainless steel, m increased from 0.22 at 25 C to 0.34 at 95 C, then decreased to about 0.23 at 125 C. With aluminum m increased from about 0.08 at 25 C to 0.48 at 115 C, then decreased slightly. Against PTFE m was sigmoidal, increasing from about 0.3 at 25 C to about at 0.49 above 115 C. Against PBX 9404 itself, m averaged 0.54 independent of temperature, but tended to increase during the measurement, probably because of adhesion of nitrocellulose to itself.