2022
DOI: 10.3390/molecules27113634
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3D Graphene Foam by Chemical Vapor Deposition: Synthesis, Properties, and Energy-Related Applications

Abstract: In this review, we highlight recent advancements in 3D graphene foam synthesis by template-assisted chemical vapor deposition, as well as their potential energy storage and conversion applications. This method offers good control of the number of graphene layers and porosity, as well as continuous connection of the graphene sheets. The review covers all the substrate types, catalysts, and precursors used to synthesize 3D graphene by the CVD method, as well as their most viable energy-related applications.

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Cited by 22 publications
(9 citation statements)
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References 87 publications
(166 reference statements)
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“…Moreover, the graphene-nanofoam-based electrode showed high specific capacitance of 321 Fg −1 for high performance supercapacitor. Zhang et al [56] proposed a route to graphene nanofoam using the template-and catalyst-based methods (Figure 2). The graphene nanofoam derived from the template method showed low density, high porosity, mechanical stability, and electrical conductivity [57].…”
Section: D Graphene Nanofoammentioning
confidence: 99%
“…Moreover, the graphene-nanofoam-based electrode showed high specific capacitance of 321 Fg −1 for high performance supercapacitor. Zhang et al [56] proposed a route to graphene nanofoam using the template-and catalyst-based methods (Figure 2). The graphene nanofoam derived from the template method showed low density, high porosity, mechanical stability, and electrical conductivity [57].…”
Section: D Graphene Nanofoammentioning
confidence: 99%
“…44 The cracking of methane on nickel catalysts is moderately endothermic and occurs at temperatures above 819 K where Δ G 0 is below zero, producing hydrogen and carbon (eqn (2)). 34 CH 4 → C + 2H 2 , Δ H (298 K) = 74.52 kJ mol −1 …”
Section: Synthesis Chemistry Of 3d Graphenementioning
confidence: 99%
“…27 Therefore, 3D graphene can avoid the restacking of graphene sheets to retain the exceptional properties of 2D graphene, making it ideal for practical applications. [31][32][33][34] This feature article provides an overview of the significant roles of 3D graphene-based materials in various components of DSSCs and PSCs, with an emphasis on 3D graphene from carbon oxides via our alkali metal chemical approaches.…”
Section: Introductionmentioning
confidence: 99%
“…The capacitance of pseudocapacitive materials is many orders of magnitude larger than that of ferroelectric materials [4]. Many pseudocapacitive materials and composites exhibit nearly rectangular cyclic voltammograms and linear chronopotentiometry dependences, indicating their ideal capacitive behavior [5][6][7]. In contrast to ferroelectric materials, low resistance is beneficial for charging supercapacitor materials [8].…”
Section: Introductionmentioning
confidence: 99%