Flexible
piezoresistive sensors with high sensitivity, low cost,
and wide response ranges are urgently required due to the rapid development
of wearable electronics. Here, carbon nanotubes (CNTs)/graphene/waterborne
polyurethane (WPU)/cellulose nanocrystal (CNC) composite aerogels
(CNTs/graphene/WC) were fabricated by facile solution mixing and freeze-drying
technology for high-performance pressure sensors. WPU and CNC were
constructed as a 3D structure skeleton, and the synergistic effect
of CNTs and graphene was beneficial to enhancing the sensing performance.
The obtained pressure sensor exhibits a highly porous network structure,
remarkable mechanical properties (76.16 kPa), high sensitivity (0.25
kPa–1), an ultralow detection limit (0.112 kPa),
and high stability (>800 cycles). More importantly, the piezoresistive
sensor could be successfully used to detect various human motions
such as finger bending, squatting–rising, walking, and running
and effectively extract real-time information by the electrical signals.
In addition, the CNTs/graphene/WC composite aerogel exhibits excellent
thermal insulation performance, which can withstand 160 °C for
a long time without any damage to the structure. The CNTs/graphene/WC
composite aerogel, because of its thermal insulation property, endows
the sensor with the potential for application in high-temperature
environments. The results indicate that CNTs/graphene/WC composite
aerogels possess high sensing performance and outstanding thermal
insulation, which means that the aerogels could be used as flexible,
wearable electronics.