Bubble
growth and detachment are basic phenomena in boiling and
water splitting processes and are essential for their heat transfer
performance and hydrogen production efficiency. In this study, we
investigate the formation and detachment of bubbles from a submerged
capillary nozzle. Here, we report a new bubbling regime and term it
unstable bubbling, where early and normal bubble detachments coexist.
The early detachment leads to the generation of many finer bubbles,
ranging from one-fifth to one-half of the volume of the permanently
detached bubbles driven by buoyancy. The occurrence conditions for
unstable bubbling are identified by developing a regime map. The visualization
of bubble-induced liquid flow and energy analysis suggest that the
oscillating detached bubble provides excess surface and kinetic energies
to the growing bubble, supporting early bubble detachment. Two dimensionless
numbers are derived considering the effect of these energies, which
can be applied to successfully predict the occurrence of early detachment.
The present results not only provide physical insight into bubble
interactions but also offer potential techniques for generating fine
bubbles.