[(3-Nitro-1H-1,2,4-triazol-1-yl)-NNO-azoxy]furazans: energetic materials containing an N(O)N–N fragment

Abstract

A novel class of energetic compounds with a N(O) N–N fragment, [(3-nitro-1H-1,2,4-triazol-1-yl)-NNO-azoxy]furazans, which exhibit good thermal stability and high experimental enthalpies of formation are estimated as possible components of solid composite propellants.

Regioselective synthesis of novel nitroso-pyrazolylquinoxalines via HOAc-mediated cyclocondensation of 2-hydroxyimino-1,3-diketones with hydrazinylquinoxalines

“…Aromatic and heteroaromatic C -nitroso compounds are versatile intermediates that are used for the synthesis of a wide range of nitrogen- and oxygen-containing compounds. For example, the oxidation of nitroso(het)arenes to nitro compounds, 1 reduction to amines 2 under mild conditions, condensations with amines and hydrazines leading to azo-, 3 azoxy- 4 compounds and triazene- N -oxides 5 have been reported. Also, the transformation of C -nitroso compounds to hydroxylamine derivatives 6 and azomethine derivatives 7 have been previously described.…”