3-D pillared clay mimics of lanthanide–organic frameworks constructed from 5-fluoroisophthalic acid and 4,4′-bipyridine through hydrogen bonds

Zhang, Zhi‐Hui; Chen, Sheng‐Chun; Mi, Jin-Ling; He, Ming‐Yang; Chen, Qun; Wu, Zenghui; Hu, Zhao-Jian

doi:10.1016/j.inoche.2010.08.010

Cited by 7 publications

(2 citation statements)

References 38 publications

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“…It crystallizes in the P 4 /mcc space group of tetragonal system with two formula molecules in one unit cell. The samarium ion coordinates to eight oxygen atoms, yielding a distorted square anti-prism with the bond length of Sm-O being of 2.407(2) Å, which is normal and comparable with those previously documented [13][14][15]. The bond angles of O-Sm-O are in a wide range of 69.17 (7)-157.11 (6)°.…”

Section: Resultssupporting

confidence: 84%

A series of thermal stable lanthanide porphyrins with a condensed three-dimensional porous open framework: Gas adsorption and magnetic properties

Huang

et al. 2015

J. Porphyrins Phthalocyanines

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A series of lanthanide porphyrins, [Ln III (TPPS IV )] n • nH 5 O 2 (Ln = La, Sm, Eu; H 2 TPPS = tetra(4-sulfonatophenyl)porphyrin), have been synthesized through solvothermal reactions and structurally characterized by single-crystal X-ray diffraction. These compounds are characterized by a condensed three-dimensional (3-D) porous open framework. Magnetic measurements reveal that these compounds show ferromagnetic, antiferromagnetic and paramagnetic behavior, respectively. All of the compounds exhibit highly thermal stability. The FT-IR and adsorption measurement of CO 2 were also studied.

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Section: Resultssupporting

confidence: 84%

A series of thermal stable lanthanide porphyrins with a condensed three-dimensional porous open framework: Gas adsorption and magnetic properties

Huang

et al. 2015

J. Porphyrins Phthalocyanines

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“…However, among these complexes, only several are samarium-containing complex with bipy [41][42][43][44][45]. …”

Section: Photoluminescence Propertiesmentioning

confidence: 99%

A novel samarium complex with interesting photoluminescence and semiconductive properties

Zhang¹,

Chen²,

F.Wang³

2018

Bull. Chem. Soc. Eth.

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ABSTRACT.[Sm(H2O)4(NO3)3](4,4'-Hbipy)2(NO3)2 (1) (bipy = bipyridine) has been synthesized via hydrothermal reaction and characterized by X-ray diffraction. The title complex features an isolated structure, based on discrete 4,4'-Hbipy moieties, isolated nitrates and [Sm(H2O)4(NO3)3] species. The samarium ion is in a distorted bicapped square antiprism environment, coordinated by three bidentate nitrates and four coordination water molecules. The 4,4'-Hbipy moieties, isolated nitrates and [Sm(H2O)4(NO3)3] species are held together via hydrogen bonds and … interactions to form a 3-D supramolecular framework. Luminescent investigation reveals a strong emission in blue region. Optical absorption spectrum of 1 reveals the presence of an optical gap of 3.60 eV.

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Ultrasound Assisted NucleophilicCyclization of Tetrafluoroterephthalonitrile: An Efficient Way to Fluorine‐Containing Heterocycles

Wang

Chen

et al. 2014

Journal of Heterocyclic Chem

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3-D pillared clay mimics of lanthanide–organic frameworks constructed from 5-fluoroisophthalic acid and 4,4′-bipyridine through hydrogen bonds

Cited by 7 publications

References 38 publications

A series of thermal stable lanthanide porphyrins with a condensed three-dimensional porous open framework: Gas adsorption and magnetic properties

A series of thermal stable lanthanide porphyrins with a condensed three-dimensional porous open framework: Gas adsorption and magnetic properties

A novel samarium complex with interesting photoluminescence and semiconductive properties

Ultrasound Assisted NucleophilicCyclization of Tetrafluoroterephthalonitrile: An Efficient Way to Fluorine‐Containing Heterocycles

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