3,4-dicarbomethoxybicyclo[3.2.2]nonatriene

Goldstein, M. J.; Gevirtz, A.H.

doi:10.1016/s0040-4039(00)71679-0

Cited by 17 publications

(6 citation statements)

References 11 publications

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“…The emission appears to accompany charge-transfer transitions from the ligand to the metal ion ( * -* d), i.e., similar in kind to that assigned by Paris and Brandt for the luminescence of the Ru(II) chelates. 1 The ultraviolet-visible absorption spectra for the Ir(III) species are shown in Figure 1. The absorption spectrum of 2,2'-bipyridine in concentrated sulfuric acid is included in Figure 1 because the diprotonated (1) J. P. Paris and W. W. Brandt, J.…”

mentioning

confidence: 99%

Luminescence of iridium(II) chelates with 2,2'-bipyridine and with 1,10-phenanthroline

Wunschel¹,

Ohnesorge²

1967

J. Am. Chem. Soc.

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mentioning

confidence: 99%

Luminescence of iridium(II) chelates with 2,2'-bipyridine and with 1,10-phenanthroline

Wunschel¹,

Ohnesorge²

1967

J. Am. Chem. Soc.

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“…Some results 193 ' 194 indicate that the former isomer (XCIV) predominates strongly, whereas others 195 " 198 show approximately equal quantities of the two isomers. The rate of the reaction depends on the nature of the halogen, decreasing in the sequence I > Br > ci 143 ' 144 ' 199 . Compounds in which the orientation of rings A and Β is cis (XCVI) also form a mixture of isomeric esters (XCVII) and(XCVm) 194 ' 200 .…”

Section: Dicyclic and Polycyclic Halogeno-ketonesmentioning

confidence: 99%

The Favorskii Rearrangement

Akhrem¹,

Ustynyuk²,

Titov³

1970

Russ. Chem. Rev.

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The skeletal rearrangement of α-halogeno-ketones, which is known as the Favorskii rearrangement, is met most frequently in aliphatic monocyclic, and poly cyclic halogenated ketones. This molecular rearrangement is used in the synthesis of branched carboxylic acids and czs-a0-unsaturated acids and for obtaining smaller rings in alicyclic and to a less extent heterocyclic compounds. The sterochemistry and the mechanism of the Favorskii rearrangement are also considered, these being of great interest for theoretical organic chemistry. A list of 261 references is included. CONTENTS

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“…Other more sophisticated orbital pictures have been devised that predict the effects of substituents on these equilibria . The presence of small equilibrium concentrations of the norcaradiene form was confirmed using Diels−Alder reactions. , …”

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confidence: 99%

7-Silylcycloheptatrienes and Analogues: Reactivity and Selectivity in Cascade Processes

2008

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7-Silyl- and 7-silylmethylcycloheptatrienes react with acylnitroso reagents at room temperature to provide the corresponding silyl- and silymethylnorcaradiene cycloadducts. Depending on the reaction conditions, 7-silylmethylcycloheptatriene was also shown to provide, through cascade processes, functionalized cyclohexa-1,3-dienes or bicyclic synthons, incorporating one and two amino groups, respectively, that may be elaborated further, for instance, into sugar mimics.

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3,4-dicarbomethoxybicyclo[3.2.2]nonatriene

Cited by 17 publications

References 11 publications

Luminescence of iridium(II) chelates with 2,2'-bipyridine and with 1,10-phenanthroline

Luminescence of iridium(II) chelates with 2,2'-bipyridine and with 1,10-phenanthroline

The Favorskii Rearrangement

7-Silylcycloheptatrienes and Analogues: Reactivity and Selectivity in Cascade Processes

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