2D Bipyrimidine silver(I) nitrate: Synthesis, X-ray structure, solution chemistry and anti-microbial activity

Massoud, Al-Shimaà A A; Langer, Vratislav; Gohar, Yousry M.; Abu‐Youssef, Morsy A. M.; Jänis, Janne; Öhrström, Lars

doi:10.1016/j.inoche.2011.01.022

Cited by 10 publications

(3 citation statements)

References 30 publications

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“…In fact, Ag(I) has been previously shown to form one-dimensional chains with the parent 2,2′bipyrimidine molecule. 29,30 The diamagnetism of Ag(I) would also facilitate solution studies by 1 H NMR spectroscopy.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…Silver(I) has a flexible geometry owing to a d 10 electron configuration, and coordination polymers of silver are of interest for antimicrobial agents, catalyst precursors, and electronic materials. In fact, Ag(I) has been previously shown to form one-dimensional chains with the parent 2,2′-bipyrimidine molecule. , The diamagnetism of Ag(I) would also facilitate solution studies by 1 H NMR spectroscopy.…”

Section: Results and Discussionmentioning

confidence: 99%

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Coordination Polymers from Functionalized Bipyrimidine Ligands and Silver(I) Salts

Beaulieu-Houle

White

MacLachlan

2018

Crystal Growth & Design

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Readily functionalizable bipyrimidine compounds were prepared for the first time, and their coordination chemistry with silver salts was explored. Solution 1H NMR spectroscopy experiments indicated that the ligands rapidly form complexes with silver(I) salts, and coordination at a first site inhibits coordination of a second cation to the ligand, thus favoring 1:1 complexes in solution. These 1:1 units self-assemble into one-dimensional chains in the solid state, even in the presence of excess Ag(I). Structurally diverse coordination polymers exhibiting different coordination numbers and geometry were characterized by single crystal X-ray crystallography. Our results demonstrate that a modification to the ligand, distal from the binding site, affects the coordination chemistry and supramolecular structure of these complexes.

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Section: ■ Results and Discussionmentioning

confidence: 99%

Section: Results and Discussionmentioning

confidence: 99%

Coordination Polymers from Functionalized Bipyrimidine Ligands and Silver(I) Salts

Beaulieu-Houle

White

MacLachlan

2018

Crystal Growth & Design

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“…Silver(I) complexes attracted the attention of many research groups due to their fascinating structure aspects as well as their interesting biological activity as antimicrobial and antifungal agents [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19]. The complexation between the organic ligand and silver(I) is considered an improvement for the ligand biological activity [20].…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Crystal Structure and Hirshfeld Topology Analysis of Polymeric Silver(I) Complex with s-Triazine-Type Ligand

Soliman

El‐Faham

2017

Crystals

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Abstract:The synthesis, single crystal X-ray diffraction (SC-XRD) characterization and Hirshfeld topology analysis of molecular packing of the coordination polymer [Ag 2 L(H 2 O) 2 (ClO 4 ) 2 ] n , where L = 2,4,6-trimorpholino-1,3,5-triazine were discussed. The asymmetric unit comprises one Ag 2 L(H 2 O) 2 (ClO 4 ) 2 unit. The coordination geometries around the two silver atoms are different where Ag(1) is hexa-coordinated with one L, two bridged water, and two bridged perchlorate augmented with one strong Ag-O interaction from the morpholine O-atom of another ligand (L) unit. The coordination environment is more like to a distorted octahedral arrangement according to the criteria of continuous shape measurements. Ag(2) is coordinated to one L, one terminal water and one terminal perchlorate leading to a distorted trigonal planar arrangement around Ag(2). Hirshfeld analysis of molecular packing indicated that the most important intermolecular contacts affect the molecular packing of the studied complex are the H...H and the O...H interactions. Atoms in molecules (AIM) and natural bond orbital (NBO) analyses were used to describe the strength and nature of the Ag-O and Ag-N interactions.

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The Diphosphorus Complex [Cp₂Mo₂(CO)₄(η²‐P₂)] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers

et al. 2016

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The three‐component reaction of the tetrahedral diphosphorus complex [Cp2Mo2(CO)4(η2‐P2)] (1), with Ag[BF4] (2) in the presence of 2,2′‐bipyrimidine (3) leads to the formation of the two novel two‐dimensional networks 4 and 5. Compound 4 is a new two‐dimensional organometallic‐organic hybrid polymer, while derivative 5 represents a unique two‐dimensional organometallic‐inorganic‐organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two‐component reactions with organic molecules in addition of metal ions.

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2D Bipyrimidine silver(I) nitrate: Synthesis, X-ray structure, solution chemistry and anti-microbial activity

Cited by 10 publications

References 30 publications

Coordination Polymers from Functionalized Bipyrimidine Ligands and Silver(I) Salts

Coordination Polymers from Functionalized Bipyrimidine Ligands and Silver(I) Salts

Synthesis, Crystal Structure and Hirshfeld Topology Analysis of Polymeric Silver(I) Complex with s-Triazine-Type Ligand

The Diphosphorus Complex [Cp₂Mo₂(CO)₄(η²‐P₂)] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers

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2D Bipyrimidine silver(I) nitrate: Synthesis, X-ray structure, solution chemistry and anti-microbial activity

Cited by 10 publications

References 30 publications

Coordination Polymers from Functionalized Bipyrimidine Ligands and Silver(I) Salts

Coordination Polymers from Functionalized Bipyrimidine Ligands and Silver(I) Salts

Synthesis, Crystal Structure and Hirshfeld Topology Analysis of Polymeric Silver(I) Complex with s-Triazine-Type Ligand

The Diphosphorus Complex [Cp2Mo2(CO)4(η2‐P2)] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers

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The Diphosphorus Complex [Cp₂Mo₂(CO)₄(η²‐P₂)] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers