2010
DOI: 10.1021/ja907220f
|View full text |Cite
|
Sign up to set email alerts
|

2D Assembly of Metallacycles on HOPG by Shape-Persistent Macrocycle Templates

Abstract: The synthesis and scanning tunneling microscopy (STM) investigations of shape-persistent arylene-ethynylene-butadiynylene macrocycles along with their codeposites with metallacycles are reported. 2D ordered arrays of macrocycles and macrocycle/metallacycle architectures (1:1) have been obtained on HOPG by self-assembly under ambient conditions. It is found that the ordered macrocycle array acts as a template for the deposition of the adlayer molecules. For each underlying macrocycle, one metallacycle has been … Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1

Citation Types

0
56
0

Year Published

2010
2010
2013
2013

Publication Types

Select...
8

Relationship

3
5

Authors

Journals

citations
Cited by 85 publications
(56 citation statements)
references
References 12 publications
0
56
0
Order By: Relevance
“…3). Various examples of co-assembly of shape-persistent macrocycles with additional molecules have been recently reported [17,2027]. Note that 1 serves as a starting material for the synthesis of 2 .…”
Section: Resultsmentioning
confidence: 99%
“…3). Various examples of co-assembly of shape-persistent macrocycles with additional molecules have been recently reported [17,2027]. Note that 1 serves as a starting material for the synthesis of 2 .…”
Section: Resultsmentioning
confidence: 99%
“…Until now, various two-dimensional molecular templates as well as designed host-guest systems have been constructed on solid supports and studied at the molecular scale by means of scanning tunnelling microscopy (STM) [36][37][38][39]. Steered by two-dimensional molecular templates, the desired patterns of C 60 , porphyrin and phthalocyanine derivatives, and many other functional molecules, have been accomplished [26,38,39]. This review focuses on the self-assemblies of a class of telechelic organic compounds which bear an aromatic core decorated with multiple alkyl chains with terminal functional groups, for instance a carboxyl group.…”
Section: Introductionmentioning
confidence: 99%
“…[1][2][3][4][5] Until now, various functional molecules have been shown to be able to self-assemble into interesting nanostructures, such as ribbons and networks, through various non-covalent interactions, including hydrogen-bonding [6][7][8][9][10][11][12][13] and van der Waals interactions [14][15][16][17][18][19][20] or metal-organic coordination. [1][2][3][4][5] Until now, various functional molecules have been shown to be able to self-assemble into interesting nanostructures, such as ribbons and networks, through various non-covalent interactions, including hydrogen-bonding [6][7][8][9][10][11][12][13] and van der Waals interactions [14][15][16][17][18][19][20] or metal-organic coordination.…”
Section: Introductionmentioning
confidence: 99%
“…Self-assembled molecular nanostructures are important candidates for functional materials and for molecule-based miniature devices. [1][2][3][4][5] Until now, various functional molecules have been shown to be able to self-assemble into interesting nanostructures, such as ribbons and networks, through various non-covalent interactions, including hydrogen-bonding [6][7][8][9][10][11][12][13] and van der Waals interactions [14][15][16][17][18][19][20] or metal-organic coordination. [21][22][23][24][25] In particular, the formation of hydrogen bonds between functional groups has been extensively explored to guide the assembly of hierarchical molecular architectures, owing to their directionality and stability.…”
Section: Introductionmentioning
confidence: 99%