Wet-Chemical Synthesis of 3D Stacked Thin Film Metal-Oxides for All-Solid-State Li-Ion Batteries

Abstract

By ultrasonic spray deposition of precursors, conformal deposition on 3D surfaces of tungsten oxide (WO 3 ) negative electrode and amorphous lithium lanthanum titanium oxide (LLT) solid-electrolyte has been achieved as well as an all-solid-state half-cell. Electrochemical activity was achieved of the WO 3 layers, annealed at temperatures of 500 • C. Galvanostatic measurements show a volumetric capacity (415 mAh·cm −3 ) of the deposited electrode material. In addition, electrochemical activity was shown for half-cells, created by coating WO 3 with LLT as the solid-state electrolyte. The electron blocking properties of the LLT solid-electrolyte was shown by ferrocene reduction. 3D depositions were done on various micro-sized Si template structures, showing fully covering coatings of both WO 3 and LLT. Finally, the thermal budget required for WO 3 layer deposition was minimized, which enabled attaining active WO 3 on 3D TiN/Si micro-cylinders. A 2.6-fold capacity increase for the 3D-structured WO 3 was shown, with the same current density per coated area.