2017
DOI: 10.1021/acsnano.7b05546
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Conductive Polymer Waving in Liquid Nitrogen

Abstract: The poor mechanical properties and processability of pristine heterocyclic conductive polymers represent the most notable scientific and technological challenges that have greatly limited the application of these polymers. We report a soft and mechanically processable free-standing pristine polypyrrole (PPy) membrane (PPy-N) that is as soft in liquid nitrogen (-196 °C) as it is at room temperature, despite a glass transition temperature (T) above 100 °C. This PPy membrane also displays a highly attractive comb… Show more

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Cited by 29 publications
(24 citation statements)
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References 39 publications
(76 reference statements)
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“…In recent years, some of the most interesting reports concern conductive hydrogels (conducting polymer hydrogels, CPHs) based on single component ICPs (PANI, PPy, Pt) as the continuous phase. Despite their unusual structures (some representative hydrogels/membranes of ICPs are presented in Figure 1) [141,147,148,149], the resulting CPHs show some novel properties, e.g., shape memory elasticity, fast functionalization with various guest objects, and fast removal of organic pollutants from aqueous solutions [148]. Furthermore, lightweight, elastic, and conductive organic sponges/hydrogels have been successfully applied in biomedical applications, which will be discussed in the following paragraphs.…”
Section: Synthesis Physicochemical and Biological Properties Of Cmentioning
confidence: 99%
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“…In recent years, some of the most interesting reports concern conductive hydrogels (conducting polymer hydrogels, CPHs) based on single component ICPs (PANI, PPy, Pt) as the continuous phase. Despite their unusual structures (some representative hydrogels/membranes of ICPs are presented in Figure 1) [141,147,148,149], the resulting CPHs show some novel properties, e.g., shape memory elasticity, fast functionalization with various guest objects, and fast removal of organic pollutants from aqueous solutions [148]. Furthermore, lightweight, elastic, and conductive organic sponges/hydrogels have been successfully applied in biomedical applications, which will be discussed in the following paragraphs.…”
Section: Synthesis Physicochemical and Biological Properties Of Cmentioning
confidence: 99%
“…Photographs of ( H , I ) synthesis of PPy hydrogel inside glass vials and ( J ) formed PPy hydrogel [148]. ( K – P ) SEM images of PPy membrane synthesized by template-assisted polymerization [149]. Reprinted with permission from References [141,147,148,149].…”
Section: Figures Schemes and Tablesmentioning
confidence: 99%
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“…The ABA-PEG20k-Pi20 polymer used in this study was synthesized de novo and verified for its ability to coat bacteria and make its phosphate available for delivery and virulence suppression 19 . In the present study, ABA-PEG20k-Pi20 was observed to deliver phosphate to the site of the anastomosis, significantly attenuate collagenolytic populations of E. faecalis at anastomotic sites and enhances anastomotic healing.…”
Section: Discussionmentioning
confidence: 99%
“…PANI possesses controlled conductivity combined with ionic and proton Fig. 1) [138], [139], [135], [137], the resulting CPHs show some novel properties, e.g., shape memory elasticity, fast functionalization with various guest objects, and fast removal of organic pollutants from aqueous solutions [138].…”
Section: Electronically Conducting Polymers (Intrinsically Conductingmentioning
confidence: 99%