Crystal structure ofcis-bis[4-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ2N1,S]nickel(II) monohydrate tetrahydrofuran disolvate

The reaction of (2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-ylidene]hydrazinecarbothioamide (common name: cinnamaldehyde-4-phenylthiosemicarbazone) deprotonated with NaOH in ethanol with an ethanolic suspension of PdII chloride in a 2:1 molar ratio yielded the title compound, [Pd(C16H14N3S)2]. The anionic ligands act as metal chelators, κ2 N 1 S-donors, forming five-membered rings with a trans-configuration. The PdII ion is fourfold coordinated in a slightly distorted square-planar geometry. For each ligand, one H...S and one H...N intramolecular interactions are observed, with S(5) and S(6) graph-set motifs. Concerning the H...S interactions, the coordination sphere resembles a hydrogen-bonded macrocyclic environment-type. In the crystal, the complexes are linked via pairs of H...S interactions, with graph-set motif R 2 2(8), and building a mono-periodic hydrogen-bonded ribbon along [001]. The Hirshfeld surface analysis indicates that the major contributions for the crystal cohesion are: H...H (45.3%), H...C/C...H (28.0%), H...S/S...H (8.0%) and H...N/N...H (7.4%).

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Crystal structure ofcis-bis[4-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ²N¹,S]nickel(II) monohydrate tetrahydrofuran disolvate

Abstract: Crystal structure of a NiII–thiosemicarbazone complex showing an unusual cis arrangement of the N,S-donor ligands and anagostic C—H⋯Ni interactions.

Cited by 3 publications

References 8 publications

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Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ²N¹,S)nickel(II)

A new example of intramolecular C—H...Ni anagostic interactions: synthesis, crystal structure and Hirshfeld analysis of cis-bis[4-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ² N ¹,S]nickel(II) dimethylformamide monosolvate

Synthesis, crystal structure and Hirshfeld analysis of trans-bis{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-ylidene]hydrazinecarbothioamidato-κ² N ¹,S}palladium(II)

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Crystal structure ofcis-bis[4-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ2N1,S]nickel(II) monohydrate tetrahydrofuran disolvate

Abstract: Crystal structure of a NiII–thio­semicarbazone complex showing an unusual cis arrangement of the N,S-donor ligands and anagostic C—H⋯Ni inter­actions.

Cited by 3 publications

References 8 publications

Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2N1,S)nickel(II)

Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ2N1,S)nickel(II)

A new example of intramolecular C—H...Ni anagostic interactions: synthesis, crystal structure and Hirshfeld analysis of cis-bis[4-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ2 N 1,S]nickel(II) dimethylformamide monosolvate

Synthesis, crystal structure and Hirshfeld analysis of trans-bis{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-ylidene]hydrazinecarbothioamidato-κ2 N 1,S}palladium(II)

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Product

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Crystal structure ofcis-bis[4-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ²N¹,S]nickel(II) monohydrate tetrahydrofuran disolvate

Abstract: Crystal structure of a NiII–thiosemicarbazone complex showing an unusual cis arrangement of the N,S-donor ligands and anagostic C—H⋯Ni interactions.

Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ²N¹,S)nickel(II)

Crystal structure of bis(acetophenone 4-benzoylthiosemicarbazonato-κ²N¹,S)nickel(II)

A new example of intramolecular C—H...Ni anagostic interactions: synthesis, crystal structure and Hirshfeld analysis of cis-bis[4-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ² N ¹,S]nickel(II) dimethylformamide monosolvate

Synthesis, crystal structure and Hirshfeld analysis of trans-bis{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-ylidene]hydrazinecarbothioamidato-κ² N ¹,S}palladium(II)