Synthesis, structure and excitation wavelength dependent PL properties of novel nanocomposite La2O2CO3·CuO·ZnO

Subhan, Abdus; Ahmed, Tanzir; Awal, Robeul; Fahim, Abul Mansur M.

doi:10.1016/j.saa.2014.05.015

Cited by 9 publications

(1 citation statement)

References 22 publications

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“…As shown in Fig. 2, no additional phases were observed, and the diffraction pattern of Gd 2 O 2 CO 3 in the NC corresponded with the literature [30,33]. It should also be noted that the crystallinity of a photocatalyst is of The functional groups present in the prepared samples were then examined by FTIR and the results are presented in Fig.…”

Section: Structural and Morphological Characterizationsupporting

confidence: 77%

Photocatalytic activity of Gd2O2CO3·ZnO·CuO nanocomposite used for the degradation of phenanthrene

et al. 2018

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Multimetal oxides nanocomposite photocatalysts based on Gd 2 O 2 CO 3 •ZnO•CuO were prepared by a co-precipitation method and carefully characterized using a range of analytical techniques. More specifically, analysis by X-ray diffraction and electron microscopies confirmed the identity and quality of the as-synthesized powders. The photocatalytic degradation activities of these nanocomposites towards phenanthrene were then investigated by measuring the effects of catalyst dosage, irradiation time, and oxidant addition. In addition, the pseudo first-order kinetic model was used to determine the rate constant of the degradation reaction. Optimum dosages of 0.6, 0.6, and 0.4 gL −1 were recorded when using CuO, Cu-CuO/ZnO, and Gd 2 O 2 CO 3 •ZnO•CuO, respectively. In addition, the Gd 2 O 2 CO 3 •ZnO•CuO composite exhibited a higher removal efficiency than both Cu-CuO/ZnO and the pure CuO nanoparticles. Furthermore, the addition of oxidants influenced the removal of phenanthrene from solution. Finally, the photocatalytic degradation data followed pseudo first-order kinetics as defined by the Langmuir-Hinshelwood model, which allowed prediction of the faster degradation rate by the Gd 2 O 2 CO 3 •ZnO•CuO nanocomposite. The newly synthesized nanocomposite could therefore be considered for the removal of phenanthrene and related polycyclic aromatic hydrocarbons from contaminated water.

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Section: Structural and Morphological Characterizationsupporting

confidence: 77%